2015) Cd(II) complexation with 1,1-dithiolate and nitrogen donors: synthesis, luminescence, crystal structure, and antifungal activity studyA new luminescent complex of Cd(II) with 1,1-dicyanoethylene-2,2-dithiolate [i-MNT 2− = {S 2 C:C (CN) 2 } 2− ] has been synthesized and characterized on the basis of spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal X-ray diffraction analysis reveals that the cadmium(II) complex is five coordinate in a 1-D polymer. Biological screening in vitro of the complex has been tested against five fungi Synchytrium endobioticum, Pyricularia oryzae, Helminthosporium oryzae, Candida albicans (ATCC10231), and Trichophyton mentagrophytes by the disk diffusion method. The antifungal activity of the complex of Cd(II) is significant compared to K 2 iMNT on S. endobioticum, P. oryzae, H. oryzae, and T. mentagrophytes and proved to be crucial for the growth-inhibitor effect.A new luminescent complex of Cd(II) with 1,1-dicyanoethylene-2,2-dithiolate [i-MNT 2− = {S 2 C : C (CN) 2 } 2− ] with 1,3-diaminopropane (tn) and 4-methyl pyridine (γ-picoline) as secondary ligands has *Corresponding author.
Downloaded by [University of Nebraska, Lincoln] at 03:23 06 April 2015been synthesized and characterized on the basis of spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal X-ray diffraction analysis reveals that cadmium(II) is five coordinate in a 1-D polymer. Biological screening effects in vitro of the synthesized complex has been tested against five fungi Synchytrium endobioticum, Pyricularia oryzae, Helminthosporium oryzae, Candida albicans (ATCC10231), and Trichophyton mentagrophytes by the disk diffusion method. A comparative study of inhibition zone values of K 2 i-MNT·H 2 O and {[Cd(tn)(iMNT)(4-MePy)]·4H 2 O} n (1) indicates that the complex exhibits antifungal activity, whereas K 2 i-MNT·H 2 O became silent on S. endobioticum, P. oryzae, H. oryzae, C. albicans (ATCC10231), and T. mentagrophytes.