Three-dimensional macro/mesoporous Co 3 O 4 -CeO 2 was prepared via a facile self-sustained decomposition of metal-organic complexes. Porous Co 3 O 4 -CeO 2 was characterized using X-ray diffraction, scanning electron microscopy/-transmission electron microscopy imaging, N 2 adsorption/ desorption and X-ray photoelectron spectroscopy to examine the morphology and microstructure to find out the cause. Co 3 O 4 -CeO 2 with the 3D hierarchical porous structure consisting of nanoparticles is a coral-like shape with a size of tens of micrometers and exhibits the hierarchically porous morphology, in which the walls of the macropores contain smaller mesopores. The catalytic performance of the porous Co 3 O 4 -CeO 2 for CO oxidation has been studied. Among the obtained catalysts, the porous Co 3 O 4 -CeO 2 with 20 wt% Co exhibits the best catalytic activity and the 50 % CO conversion can be reached at 74°C. The presence of transition metal element Co can promote the production of oxygen vacancies and improve oxygen mobility, which result in enhancing the oxygen-storage capacity of porous Co 3 O 4 -CeO 2 and its catalytic performance for CO conversion.
Graphical Abstract& Yude Wang