Metal atom reactions with fluorocarbons. II. Defluorination by calcium atoms1, 2

Klabunde, Kenneth J.; Low, James Y. F.; Key, Min-Suk

doi:10.1016/s0022-1139(00)83508-3

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Oxidative Addition Processes1

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2016

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Cited by 26 publications

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“…28 Only unsaturated fluorocarbons reacted in this way, however, with saturated compounds being totally inert and unsaturated compounds reacting almost quantitatively. 28 Only unsaturated fluorocarbons reacted in this way, however, with saturated compounds being totally inert and unsaturated compounds reacting almost quantitatively.…”

Section: Oxidative Addition Processesmentioning

confidence: 99%

Alkaline Earth Metals, Metal Halides, Oxides, and Sulfides (Group IIA)

Klabunde

1980

Chemistry of Free Atoms and Particles

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Section: Oxidative Addition Processesmentioning

confidence: 99%

Alkaline Earth Metals, Metal Halides, Oxides, and Sulfides (Group IIA)

Klabunde

1980

Chemistry of Free Atoms and Particles

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Nucleophilic Additions of Perfluoroalkyl Groups

Beier

Zibinsky²,

Prakash

2016

Organic Reactions

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The trifluoromethyl and perfluoroalkyl functional groups possess significant thermal, chemical, and metabolic stability, as well as high lipophilicity and electronegativity. These physicochemical properties render fluorinated carbon residues indispensable in diverse applications, such as agrochemistry, drug design, and material chemistry. The generation and properties of nucleophilic perfluoroalkyl reagents as well as the scope and limitations of their additions to various electrophilic partners is described in this chapter.

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Oxidative Additions to Metal Atoms and Slurries

Klabunde¹

1998

Inorganic Reactions and Methods

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Metal atom reactions with fluorocarbons. II. Defluorination by calcium atoms1, 2

Cited by 26 publications

References 3 publications

Alkaline Earth Metals, Metal Halides, Oxides, and Sulfides (Group IIA)

Alkaline Earth Metals, Metal Halides, Oxides, and Sulfides (Group IIA)

Nucleophilic Additions of Perfluoroalkyl Groups

Oxidative Additions to Metal Atoms and Slurries

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