Metal-catalyzed additions of H–P(O) bonds to carbon–carbon unsaturated bonds

Aerobic addition of secondary phosphine oxides to vinyl sulfides: a shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides

“…Among them, the addition of P(X)–H (X = none, O, S or Se) to diverse alkenes is one of the most powerful and 100% atom-economic approaches to construct new C–P bonds, that provide straightforward access to tertiary phosphines and their chalcogenides [8–12]. Conventionally, the activation of the P–H bonds in this reaction is achieved by using radical initiators [13–15], Brønsted/Lewis acids [16–17] and bases [18–20] as well as transition metal catalysts [21–23]. Also, examples of the microwave-assisted [24–25] and photoinduced [26] addition are described.…”

Green synthesis of tertiary alkylselanylphosphine chalcogenides via catalyst- and solvent-free addition of secondary phosphine chalcogenides to vinyl selenides

“…[1][2][3][4][5][6][7][8][9] As a rule, these reactions proceed in the presence of catalysts (bases, [2,10] radical initiators [1][2][3]5,11] or metallocomplexes [4,[6][7][8]) and in organic solvents. In recent years, catalyst-and solvent-free reactions attract particular attention.…”

Spontaneous Vesicle Formation of Monododecenyl Phosphonic Acid in Water

“…Concentration-dependent a 1 H and b31 P NMR spectra of PC 12 D 2 O, 25. Images of the PC 12 vesicles obtained with c FF-TEM 5.0 10 2 M , d phase-contrast, and e polarised microscopy 1.7 10 1 M .…”