Metal Complexes of Dithiocarbamate Derivatives and its Biological Activity

Abstract

In chelate complexes the metal ion performs a coordination with two or more donor atoms of the same ligand. The chelate impact means preferring metal ions in order to create complexes with chelating ligand instead of non-chelating ones in which the two types of ligands are capable of forming bonds of similar strength. The impact of the chelate is influenced by the effects of enthalpy and entropy [1]. Metal complexes of oxygen, sulfur and nitrogen-chelating ligands gained consideration owing to their curiously explanatory [2], biological [3] and physico-chemical [4], properties, articulated biological activities and for their utility as models of metalloenzyme dynamic sites [5]. In coordination of metals, sulfur and nitrogen atoms play a key part at the dynamic destinations of various metallobimolecules [6]. The intrigued in sulfur given chelating operators have developed exceptionally rapidly [7]. Coordination chemistry is centered on potential applications of macrocylic thio Schiff bases and their metal complexes [8]. Dithiocarbamates are very common compounds binding strongly and selectively to a wide range of metal ions, therefore, in the past decade self-assembly which is controlled by the MINI REVIEW Metal Complexes of Dithiocarbamate Derivatives and its Biological Activity

Synthesis, Theoretical Calculation, and Biological Studies of Mono- and Diphenyltin(IV) Complexes of N-Methyl-N-hydroxyethyldithiocarbamate

“…Metal dithiocarbamate and its derivatives have continued to attract growing research attention due to their diverse structural variations, unique coordination chemistry, and wide biological properties [1][2][3][4][5][6]. Their organometallic derivatives such as the organotin(IV) dithiocarbamate complexes have been reported to possess interesting properties which include the possibility for ligand exchange, structural diversity, catalytic and redox capacity, and a variety of useful medicinal properties [7].…”

Synthesis, Characterisation and Biological Activity of New Co, Ni, Zn and Cd Polymeric Complexes Derived from Dithiocarbamate Ligand

“…Two sulphur donor atoms present in dithiocarbamate ligands efficiently form chelating compounds with all metal ions 18,19 . Due to the strength of their O-bond, dithiocarbamate molecules are capable of stabilising metal ions with a high oxidation state in metal complexes.…”

Synthesis and Growth Stimulating Activity of Dithiocarbamine Thioanhydrides Based on Sodium 5-Methyl-1h-Benzotriazol-1-Carbodithioate

“…Dithiocarbamate metal compounds show also the vast array of biological properties. Notable among these are their antioxidant (Gölcü, 2006), antileishmanial (Hayat et al, 2022), antibacterial (Ahmed, 2018), antifungal activity (Hussain Dar et al, 2021). We had previously reported about synthesis of dithiocarbamates with root-forming and growth-stimulating activity (Sycheva et al, 2018).…”