Wherever humans are present artificial light is used. It allows us to live and work indoors and outdoors at any time of the day. In densely populated areas, this literally lights up our planet as is clearly seen from outer space in figure 1. The 30 billion lamps operating worldwide are certainly a great commodity, but they come at a price. Not only do they cause serious light pollution, disturbing animal and plant life, they also have a huge energy need. Of the annual world electricity production, which is more than 1013 kWh, about 15-20 % is used for lighting applications [l]. A medium-to large-sized electricity plant has a production capacity of about one GW. An easy calculation shows that a few hundred electricity plants are operating continuously solely to supply the power for our lamps. Apart from depleting fuel reserves, this also results in an annual CO2 emission of about a billion ton and the attendant effects on ecology and climate. Obviously, lighting has a large social, economical as well as ecological impact.The best known lamp type is the incandescent lamp, where an electrical current heats a wire until it lights up. More than 100 years after Edison's invention, modern incandescent lamps are still not very efficient. Incandescent lamps produce only about 3% of all light whereas they consume 20% of the power needed for lighting. Discharge lamps are about 5 to 10 times more efficient. They can be grouped into two large families based on operating pressure. Tubular fluorescent lamps, commonly used in offices, are the bestknown example of low pressure lamps. High pressure lamps are commonly used if much light is needed, such as outdoor lighting. About 97% of all artificial light on Earth is produced using plasma technology [l, 21. Evidently, plasma lamps are essential in lighting, and any increase in their efficiency, even by as little as l%, has a large impact on preserving our natural resources and environment.The metal halide lamp is a high-pressure gas discharge lamp with a very high efficiency. Despite the fact that the lamp is widely used in outdoor lighting there are still several technological and scientific problems limiting its applicability. Some of the problems are related to a poor understanding of the physics of the gas discharge. Color separation, discussed here is one of them. But before describing the problem and discussing some experiments one should first review the basics of a metal halide lamp.A Fig. 2: A schematic view of a metal halide lam*p.The arc is produced between two tungsten electrodes in a mercury buffer gas of about 10 bar.The arc is confined inside an SiO, or AI, O, burner. Furthermore, a metal halide salt like Nal, Dyl ,, Sc13, orTll is added.After evaporation and dissociation, the excited metal atom is the main radiation source.
Metal Halide LampsA metal halide lamp is derived from the better known mercury high-pressure arc discharge [2]. A schematic picture is shown in Fig. 2. An electric arc is maintained between two electrodes, which are sealed into the confming spa...