Metal organic framework/polyelectrolyte composites for water vapor sorption applications

Abstract

Metal-organic framework (MOF) core particles of MIL-101(Cr), aluminum fumarate (Basolite A520), MIL-53-TDC, zirconium fumarate, and UiO-66 were modified by adsorption of thin polyelectrolyte (PE) based shells without deterioration of their...

Enhanced catalytic activity of zeolitic imidazolate frameworks (ZIF-8) polyelectrolyte complex composites membranes by laser etching

“…Notably, one significant advantage of PDDA/PSS PECs is their excellent stability against dissolution in most organic solutions [9,10]. PDDA/PSS PECs can be used as a matrix for the immobilization of various fillers such as conducting particles (carbon black), redox species (MnO2), or even catalytic particles such as metal-organic frameworks [11][12][13]. The filler, which is usually found inside the membranes, has limited access to the solution, thus reducing the interaction between the filler particle and the solution if needed, for example, for catalytic particles.…”

Nonsteroidal anti-inflammatory drug monitoring in serum: a Tb-MOF-based luminescent mixed matrix membrane detector with high sensitivity and reliability

“…[31][32][33][34] Functional nanoparticles, such as quantum dots, MOFs, and metal oxides, can be doped into polymer solutions, and then functional nanofiber membranes can be prepared by electrostatic spinning, which have the advantages of both materials. [35][36][37][38] In this work, mixed matrix membranes (MMMs) based on Tb-MOFs and electrospinning technology were prepared and developed into a sensing platform for the rapid detection of diclofenac in serum. The as-synthesized Tb-MOFs, with good crystallinity, were rapidly obtained under ultrasonic conditions and at room temperature in only 30 min, and the prepared MMMs showed good stimulation response and repeatability towards DCF.…”

“…31–34 Functional nanoparticles, such as quantum dots, MOFs, and metal oxides, can be doped into polymer solutions, and then functional nanofiber membranes can be prepared by electrostatic spinning, which have the advantages of both materials. 35–38…”

A rapid self-healing glassy polymer/metal–organic-framework hybrid membrane at room temperature

“…[10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26] To transform laboratory-synthesized MOF powders into industrially viable products, much effort has been devoted to constructing MOF-polymer hybrid materials that not only retain the inherent properties of their individual components, but also possess some collaboratively enforced functions beyond these discrete composites. [27][28][29][30][31][32][33] For example, polymers endow MOFs powders with desired processability and flexibility; on the other hand, in addition to display functions, MOFs may also act as multiconnected cross-linking agents to further enhance the mechanical strength of the polymer. 34,35 In some cases, polymers rich in hydrogen bonds or dynamic covalent bonds also bring self-healing abilities to the hybrid materials; 36 however, an external energy input, such as heating, is required.…”