2022
DOI: 10.1016/j.trac.2022.116573
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Metal-organic frameworks as an alternative smart sensing platform for designing molecularly imprinted electrochemical sensors

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Cited by 53 publications
(24 citation statements)
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“…It has recently received significant attention owing to its high selectivity and sensitivity toward targets. Applications of MIP have been demonstrated in drug delivery, , solid-phase extraction coupled with liquid chromatography, , catalysis, , and environmental and biomedical sensing. Various techniques have been utilized to synthesize MIP layers, including free-radical polymerization, chemical grafting, soft lithographies, molecular self-assembly, and electropolymerization. , Among these techniques, electropolymerization is a practical approach for MIP synthesis because a target molecule can be added to the electrolyte and entrapped in a conductive polymeric film. The molecules are sequentially extracted or leached out of the external polymeric surfaces to create recognition sites for MIP.…”
Section: Introductionmentioning
confidence: 99%
“…It has recently received significant attention owing to its high selectivity and sensitivity toward targets. Applications of MIP have been demonstrated in drug delivery, , solid-phase extraction coupled with liquid chromatography, , catalysis, , and environmental and biomedical sensing. Various techniques have been utilized to synthesize MIP layers, including free-radical polymerization, chemical grafting, soft lithographies, molecular self-assembly, and electropolymerization. , Among these techniques, electropolymerization is a practical approach for MIP synthesis because a target molecule can be added to the electrolyte and entrapped in a conductive polymeric film. The molecules are sequentially extracted or leached out of the external polymeric surfaces to create recognition sites for MIP.…”
Section: Introductionmentioning
confidence: 99%
“…19 In line with our aim to develop an electroanalytical quanti-cation method for sugammadex, we developed an electrochemical sensor for the determination of sugammadex by using molecular imprinting via the EP technique. The EP-MIP(SUG)/ SPAuE was fabricated by using the 4-aminophenol (4-AP) monomer with copper ions 20 to enhance the MIP-binding site. The developed MIP-integrated electrochemical sensors have been used during method development and validation studies and the method was applied to pharmaceutical dosage forms and commercial serum samples to determine the amount of sugammadex.…”
Section: Introductionmentioning
confidence: 99%
“…So, modifying the electrode surface with advanced materials before preparing MIPs on the electrode is crucial to increase the electron migration rate or the active surface area of the electrode to enhance the performance of the electrode. 15,16…”
Section: Introductionmentioning
confidence: 99%
“…So, modifying the electrode surface with advanced materials before preparing MIPs on the electrode is crucial to increase the electron migration rate or the active surface area of the electrode to enhance the performance of the electrode. 15,16 Zeolite imidazolate framework-67 (ZIF-67) with large specic surface area, suitable porosity, good stability and biocompatibility has received much attention from researchers in recent years. [17][18][19] ZIF-67 with specially regular morphology could be an excellent substrate for MIP preparation.…”
Section: Introductionmentioning
confidence: 99%