Metal-organic frameworks based solid-state electrolytes for lithium metal batteries: Modifications and future prospects

Liu, Mingjie; Liu, Tengfei; Xu, Junling; Shao, Lianyi; Shi, Xiaoyan; Sun, Zhipeng

doi:10.1016/j.nxener.2024.100191

Next Energy

2025

DOI: 10.1016/j.nxener.2024.100191

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Metal-organic frameworks based solid-state electrolytes for lithium metal batteries: Modifications and future prospects

Mingjie Liu,

Tengfei Liu,

Junling Xu

et al.

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Cited by 3 publications

References 140 publications

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Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries

Yao,

Guo,

Yang

et al. 2024

Adv Funct Materials

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Electrolyte additives (EAs) are cost‐effective for stabilization of lithium metal batteries (LMBs). Nevertheless, most EAs are gradually consumed during the lithium deposition process, rendering them inadequate for long‐term cyclability. Herein, a novel hybrid metal–organic framework (MOF)‐based non‐expendable additive is prepared through polymerization of pentaerythritol tetraacrylate (PETEA) on a zeolitic imidazolate framework (ZIF‐67). Owing to the partial coating by PETEA‐based polymer, the exposed unsaturated metal sites of ZIF‐67 still attenuate the interaction between lithium ions (Li+) and anions, enabling rapid electrochemical kinetics and uniform Li deposition. Concurrently, the polymerized PETEA partially enters the Li+ solvation sheath and expels some organic solvents through Van der Waals interactions, which promotes the derivation of an inorganic‐rich SEI and inhibits dendrite formation. Accordingly, this additive‐contained Li||Li symmetric cell exhibits a stability over 1200 h with a small overpotential of 75 mV. Additionally, the assembled Li||LiFePO4 full cells with negative/positive ratio of 1.76 delivers a stable cyclability over 400 cycles at 0.5 C. Moreover, the Li||LiNi0.8Mn0.1Co0.1O2 high‐voltage full cell displays an impressive capacity retention of 80% over 311 cycles at 0.5 C. This study provides a valuable guidance to design non‐expendable multifunctional EAs for advancing high‐performance LMBs.

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Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries

Yao,

Guo,

Yang

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

Engineering a highly conductive honeycomb network on carbon cloth-supported bimetallic sulfide nanorod arrays for flexible solid-state asymmetric supercapacitors with superior performance

Liu,

Zuo,

Wang

2024

Chemical Engineering Journal

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A spontaneous spatial network structural metal-organic framework composite polymer electrolytes with excellent lithium transport performance for dendrite-suppressing lithium metal batteries

Liu,

Zhi

et al. 2024

Chemical Engineering Journal

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Metal-organic frameworks based solid-state electrolytes for lithium metal batteries: Modifications and future prospects

Cited by 3 publications

References 140 publications

Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries

Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries

Engineering a highly conductive honeycomb network on carbon cloth-supported bimetallic sulfide nanorod arrays for flexible solid-state asymmetric supercapacitors with superior performance

A spontaneous spatial network structural metal-organic framework composite polymer electrolytes with excellent lithium transport performance for dendrite-suppressing lithium metal batteries

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