Metal-Organic Frameworks in Russia:  From the Synthesis and Structure  to Functional Properties and Materials

Agafonov, Mikhail; Alexandrov, Eugeny V.; Artyukhova, N. A.; Бекмухамедов, Г. Э.; Блатов, В. А.; Butova, Vera V.; Gayfulin, Yakov M.; Garibyan, A. A.; Gafurov, Zufar N.; Gorbunova, Yulia G.; Gordeeva, Larisa G.; Груздев, М. С.; Гусев, А. Н.; Denisov, Gleb L.; Dybtsev, Danil N.; Enakieva, Yu. Yu.; Kagilev, Alexey A.; Kantyukov, Artyom O.; Кискин, М. А.; Kovalenko, Konstantin A.; Kolker, A. M.; Kolokolov, Daniil I.; Litvinova, Yulia M.; Lysova, Anna A.; Maksimchuk, Nataliya V.; Mironov, Yu. V.; Nelyubina, Yu. V.; Novikov, Valentin V.; Овчаренко, В. И.; Пискунов, А. В.; Polyukhov, Daniil M.; Polyakov, V. E.; Пономарева, В. Г.; Poryvaev, Artem S.; Романенко, Г. В.; Солдатов, А. В.; Solovyeva, Marina V.; Stepanov, Alexander G.; Терехова, И. В.; Trofimova, O. Yu.; Федин, В. П.; Fedin, Matvey V.; Kholdeeva, Oxana A.; Tsivadze, А. Yu.; Chervonova, U. V.; Черевко, А. И.; Шульгин, В. Ф.; Shutova, E. S.; Yakhvarov, Dmitry G.

doi:10.1134/s0022476622050018

Cited by 56 publications

(4 citation statements)

References 710 publications

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“…Coordination polymers are formed by binding metal ions or metal-containing cores with bridging ligands, whose variation in structure-forming parameters allows for control over the polymer's structure [1][2][3][4][5][6][7][8][9][10], as well as luminescent [11][12][13][14], sorption [4,[15][16][17][18], magnetic [19][20][21][22], and other properties. Iron(II) coordination polymers exhibit selective catalytic activity in the hydroboration of aldehydes and ketones [23], the oxidative functionalization of alkanes [24], and in dimerization reactions of aromatic halogen derivatives [25].…”

Section: Introductionmentioning

confidence: 99%

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Bushuev,

Gogoleva,

Nikolaevskii

et al. 2024

Molecules

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Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe2(piv)4(phen)2] (1) (piv = (Me)3CCO2−)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [Fe3O(piv)6(dahx)1.5]n (2) and an organic salt of pivalic acid (H2dahx)(piv)2 (3). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis. According to the single-crystal X-ray analysis, coordination polymer 2 is formed due to the binding of a triangular carboxylate core {Fe3(μ3-O)(μ-piv)6} with an aliphatic diamine ligand. Thermal behavior was investigated for compounds 1 and 2 in an argon atmosphere.

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Section: Introductionmentioning

confidence: 99%

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Bushuev,

Gogoleva,

Nikolaevskii

et al. 2024

Molecules

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“…1,2 Thus, they demonstrate excellent efficiency in gas separation and storage, catalysis, chemical sensing, drug delivery, energy technologies, agriculture, etc . 3–11 Along with the enormous progress in the research of MOFs and COFs, great attention has been paid to hydrogen-bonded organic frameworks (HOFs): the related class of assemblies based on organic or metal-containing organic compounds connected by hydrogen bonds. 12 An easier synthetic procedure, simple recrystallization and minimized environmental impact of HOFs compared with MOFs and COFs are key factors for intensive growth of research on these materials.…”

Section: Introductionmentioning

confidence: 99%

An anionic porphyrinylphosphonate-based hydrogen-bonded organic framework: optimization of proton conductivity through the exchange of counterions

et al. 2023

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“…Metal–organic frameworks are porous materials that remain the focus of many researchers due to their tunable properties [ 1 , 2 , 3 , 4 , 5 ] and applications in various fields such as catalysis [ 6 , 7 ], gas storage [ 8 , 9 , 10 ], drug delivery [ 11 , 12 , 13 ], waste scavenging [ 14 , 15 ], etc. Among the wide variety of MOFs, UiO-66 is among the most promising due to its high stability and porosity and its unique (de)hydroxylation behavior [ 16 , 17 ].…”

Section: Introductionmentioning

confidence: 99%

In Situ FTIR Spectroscopy for Scanning Accessible Active Sites in Defect-Engineered UiO-66

et al. 2023

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Three UiO-66 samples were prepared by solvothermal synthesis using the defect engineering approach with benzoic acid as a modulator. They were characterized by different techniques and their acidic properties were assessed by FTIR spectroscopy of adsorbed CO and CD3CN. All samples evacuated at room temperature contained bridging μ3-OH groups that interacted with both probe molecules. Evacuation at 250 °C leads to the dehydroxylation and disappearance of the μ3-OH groups. Modulator-free synthesis resulted in a material with open Zr sites. They were detected by low-temperature CO adsorption on a sample evacuated at 200 °C and by CD3CN even on a sample evacuated at RT. However, these sites were lacking in the two samples obtained with a modulator. IR and Raman spectra revealed that in these cases, the Zr4+ defect sites were saturated by benzoates, which prevented their interaction with probe molecules. Finally, the dehydroxylation of all samples produced another kind of bare Zr sites that did not interact with CO but formed complexes with acetonitrile, probably due to structural rearrangement. The results showed that FTIR spectroscopy is a powerful tool for investigating the presence and availability of acid sites in UiO-66, which is crucial for its application in adsorption and catalysis.

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Metal-Organic Frameworks in Russia: From the Synthesis and Structure to Functional Properties and Materials

Cited by 56 publications

References 710 publications

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

An anionic porphyrinylphosphonate-based hydrogen-bonded organic framework: optimization of proton conductivity through the exchange of counterions

In Situ FTIR Spectroscopy for Scanning Accessible Active Sites in Defect-Engineered UiO-66

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