Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review

Iulianelli, Adolfo; Ribeirinha, Paulo; Mendes, Adélio; Basile, Angelo

doi:10.1016/j.rser.2013.08.032

Cited by 429 publications

(187 citation statements)

References 148 publications

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“…Mastalir et al [82] evaluated the reaction rate coefficients of the above three reactions. The Arrhenius equations are shown in Equations (4)- (6).…”

Section: Reaction Mechanism Of Methanol Steam Reformingmentioning

confidence: 99%

“…Onboard hydrogen production by a processing system which converts liquid hydrocarbon fuels into hydrogen is a practical solution [4,5]. Among various fuels, methanol receives attention for onboard processing applications because: (a) It is easy to handle and store; (b) It can be extracted from renewable sources and it is biodegradable; (c) Its reforming temperature is relatively low compared to the other fuels; and (d) Its tendency to form coke during reforming is low due to the high H/C ratio [6,7].…”

Section: Introductionmentioning

confidence: 99%

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Review on Copper and Palladium Based Catalysts for Methanol Steam Reforming to Produce Hydrogen

Shuai

2017

Catalysts

109

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Abstract:Methanol steam reforming is a promising technology for producing hydrogen for onboard fuel cell applications. The methanol conversion rate and the contents of hydrogen, carbon monoxide and carbon dioxide in the reformate, significantly depend on the reforming catalyst. Copper-based catalysts and palladium-based catalysts can effectively convert methanol into hydrogen and carbon dioxide. Copper and palladium-based catalysts with different formulations and compositions have been thoroughly investigated in the literature. This work summarized the development of the two groups of catalysts for methanol steam reforming. Interactions between the activity components and the supports as well as the effects of different promoters were discussed. Compositional and morphological characteristics, along with the methanol steam reforming performances of different Cu/ZnO and Pd/ZnO catalysts promoted by Al 2 O 3 , CeO 2 , ZrO 2 or other metal oxides, were reviewed and compared. Moreover, the reaction mechanism of methanol steam reforming over the copper based and palladium based catalysts were discussed.

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“…Mastalir et al [82] evaluated the reaction rate coefficients of the above three reactions. The Arrhenius equations are shown in Equations (4)- (6).…”

Section: Reaction Mechanism Of Methanol Steam Reformingmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Review on Copper and Palladium Based Catalysts for Methanol Steam Reforming to Produce Hydrogen

Shuai

2017

Catalysts

109

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“…Examples of these structures include solid phase systems, such as Electronic supplementary material The online version of this article (https://doi.org/10.1007/s11244-018-0894-5) contains supplementary material, which is available to authorized users. metal and non-metal hydrides [7], amines [8], amides [9], ammonia-like complexes [10], and liquid carriers such as N-ethylperhydrocarbazole [11], alcohols [12] or formic acid.…”

Section: Introductionmentioning

confidence: 99%

“…Catalytic hydrolysis of sodium and lithium borohydrides as well as ammonia borane have been widely studied because it provides a safe and low cost route to the production of hydrogen [10][11][12][13]. Ammonia decomposition has been also studied at temperatures below 500 K showing a significant reduction in activation energy when using carbon nanotubes catalysts promoted with cesium [14].…”

Section: Introductionmentioning

confidence: 99%

Hydrogen Generation from Additive-Free Formic Acid Decomposition Under Mild Conditions by Pd/C: Experimental and DFT Studies

et al. 2018

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Safe and efficient hydrogen generation and storage has received much attention in recent years. Herein, a commercial 5 wt% Pd/C catalyst has been investigated for the catalytic, additive-free decomposition of formic acid at mild conditions, and the experimental parameters affecting the process systematically have been investigated and optimised. The 5 wt% Pd/C catalyst exhibited a remarkable 99.9% H 2 selectivity and a high catalytic activity (TOF = 1136 h −1 ) at 30 °C toward the selective dehydrogenation of formic acid to H 2 and CO 2 . The present commercial catalyst demonstrates to be a promising candidate for the efficient in-situ hydrogen generation at mild conditions possibiliting practical applications of formic acid systems on fuel cells. Finally DFT studies have been carried out to provide insights into the reactivity and decomposition of formic acid along with the two-reaction pathways on the Pd (111) surface.

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“…W skali przemysłowej największe ilości wodoru otrzymuje się w wyniku konwersji gazu ziemnego [4,6] w obecności pary wodnej i katalizatora. Obserwuje się postępy w technologii konwersji różnych surowców [13,55] i metanolu [26] do wodoru, ale największe zainteresowanie w ostatnich latach wzbudza otrzymywanie wodoru na drodze fotokatalitycznego rozkładu wody z zastosowaniem odnawialnej energii słonecznej [9,22,25]. W ocenie autorów najlepszym źródłem informacji na temat postępów w przechowywaniu wodoru jest monografia [62].…”

Section: Wodór Jako Paliwounclassified

Nowe materiały i procesy w konwersji oraz przechowywaniu energii – wybrane zagadnienia

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Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review

Cited by 429 publications

References 148 publications

Review on Copper and Palladium Based Catalysts for Methanol Steam Reforming to Produce Hydrogen

Review on Copper and Palladium Based Catalysts for Methanol Steam Reforming to Produce Hydrogen

Hydrogen Generation from Additive-Free Formic Acid Decomposition Under Mild Conditions by Pd/C: Experimental and DFT Studies

Nowe materiały i procesy w konwersji oraz przechowywaniu energii – wybrane zagadnienia

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