Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds

Zavarize, Danilo Gualberto; Braun, Heder; Oliveira, Jorge Diniz de

doi:10.1016/j.renene.2021.02.112

Cited by 10 publications

(4 citation statements)

References 70 publications

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“…BDSCCs can also serve as dual-functional catalysts for simultaneous esterification and transesterification reactions, particularly in converting waste materials like FOG into biodiesel. 103,104 These catalytic processes demonstrate excellent catalytic performance, while some sulfonated biochars exhibit significant activity loss during the application process for biodiesel, especially after multiple uses. 43,49,53 This may be mainly due to the formation of sulfonic acid esters during the reaction process in alcohol as the medium, on the one hand.…”

Section: Biodiesel Productionmentioning

confidence: 99%

Biomass derived sulfonated carbon catalysts: efficient catalysts for green chemistry

Zhu,

Ke,

et al. 2024

Green Chem.

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Section: Biodiesel Productionmentioning

confidence: 99%

Biomass derived sulfonated carbon catalysts: efficient catalysts for green chemistry

Zhu,

Ke,

et al. 2024

Green Chem.

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“…Abdullah et al prepared biodiesel employing waste cooking oil (WCO) using empty fruit bunch-based activated carbon with the biodiesel yield of 97.1% . Gualberto Zavarize et al reported an acid catalyst derived exploiting Amazon açaí berry seeds for producing biodiesel using spent cooking oil with 89% conversion . Roslan et al prepared biodiesel with 97% conversion from used cooking oil using sulfonated resin in 2 h reaction time .…”

Section: Introductionmentioning

confidence: 99%

“…23 Gualberto Zavarize et al reported an acid catalyst derived exploiting Amazon acai ́berry seeds for producing biodiesel using spent cooking oil with 89% conversion. 24 Roslan et al prepared biodiesel with 97% conversion from used cooking oil using sulfonated resin in 2 h reaction time. 25 A thorough review of the many works published in the last few years indicates that the use of biogenic precursor tamarind seeds for synthesizing carbonaceous char toward impregnation of catalyst has not been reported so far for esterifying used cooking oil to manufacture biodiesel (Figure 1 shows reaction mechanism).…”

Section: ■ Introductionmentioning

confidence: 99%

Evaluating the Scale-Up Potential of Biogenic Heterogeneous Catalyst for Biodiesel Production

Ghosh,

Rokhum

et al. 2024

ACS Sustainable Resour. Manage.

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The increasing global population and its associated energy requirements significantly burden natural energy resources. The Paris Agreement's promises to prevent global warming and promote sustainable development are obscured by the fossil fuel industry's frightening rate of exploitation. Biodiesel offers a sustainable substitute for fossil fuels to solve viable fuel and socioeconomic issues. Diverse feedstocks, including Jatropha oil, palm oil, used frying oil, edible oil, animal fat, and microbial oil, are used to make biodiesel. Much exploration has been done on creating innovative and sustainable biodiesel synthesis technologies to boost the yield of biodiesel to remain competitive. In the current investigation, tamarind seed (Tamarindus indica) derived sulfonated doped carbon catalyst was utilized for the transformation of used cooking oil methyl ester (UCOME). The morphological and spectral analyses of the produced catalyst were performed thoroughly by means of TGA, BET, FTIR, XRD, and SEM-EDAX. The study of optimization of parameters that impact biodiesel efficacy was conducted using response surface methodology, which gave 98.97% conversion. The esterification reaction was examined by two kinetic models, and it followed the pseudo-first-order reaction kinetics with the reaction being endothermic and not spontaneous. The catalyst exhibited good reusability with 81.17% conversion until 4 cycles. The deactivation study of the prepared sulfonated catalyst (SDC) was analyzed. Additionally, fuel was ascertained by GC−MS, 1 H NMR, and FTIR evaluations. The anticipated cost of 1 kg catalyst and 1 L UCOME, as determined by cost analysis, were $3.706 and $0.403, respectively, demonstrating their excellent economic viabilities.

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“…Depletion of fossil reserves increases interest to search for alternative fuel, which have same properties as diesel, to replace such fossil fuel (Andrijanto (2012) ). Among the renewable energy sources, biodiesel is ranked the best alternative to diesel fuel (Zavarize et al (2021) ). Biodiesel has been de ined as a mono-alkyl ester of vegetable oils or animal fats.…”

Section: Introductionmentioning

confidence: 99%

Application of Response Surface Methodology for the Optimization of Biodiesel Production via Transesterification of Castor Oil With Calcium Oxide

Atadashi

Darius

2021

Int. J. Res. Granthaalayah

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Castor seeds were processed and the oil was extracted from the paste by cold pressing and the yield obtained was 42.80%. Moisture content of 4.38% was found. The crude oil was obtained as clear, viscous, pale-yellow liquid. of crude castor oil with methanol to produce in the presence of calcium oxide (CaO) as a catalyst was carried out. This study the fuel properties of ; the FTIR spectrum for the revealed the functional groups with characteristics bands, C=O, (CH2) n-, C-O, C=C, OH and C-H in the spectrum. From the result of the FTIR and GC-MS, the methyl ester groups present in the produced was determined and 9-Octadecenoic acid-12-hydroxy- methyl ester was identified as the most abundant compound in the which have all the functional groups as revealed by the FTIR. The experimental design as well as statistical analysis were done and using Response Surface Methodology (RSM) design expert 12.0 version software which was also used for the optimization of the three process parameters. The optimum conditions for production were a reaction temperature of 620C, methanol to oil ratio of 11:1 and a catalyst of 3.5 of oil at 1hour. The content under these optimum conditions was 54%. R2 value of 0.9996 was obtained showing good fitting

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Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds

Cited by 10 publications

References 70 publications

Biomass derived sulfonated carbon catalysts: efficient catalysts for green chemistry

Biomass derived sulfonated carbon catalysts: efficient catalysts for green chemistry

Evaluating the Scale-Up Potential of Biogenic Heterogeneous Catalyst for Biodiesel Production

Application of Response Surface Methodology for the Optimization of Biodiesel Production via Transesterification of Castor Oil With Calcium Oxide

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