Few houses have been built in the Spanish Mediterranean in accordance with the Passivhaus (PH) standard. This standard is adapted to the continental climates of Central Europe and thorough studies are necessary to apply this standard in Spain, especially in the summer. High relative air humidity levels in coastal areas and solar radiation levels of west-facing façades require adapted architectural designs, as well as greater control of air renewal and dehumidification. A priori, energy consumptions undergo big variations. In this study, the construction of a single-family house in the Spanish Levante was analysed. All enclosure layers were monitored using sensors of surface temperature, solar radiation, indoor and outdoor air temperature, relative humidity, and air speed. The thermal behaviour of the façade enclosure and air infiltration through the enclosure were examined using the blower door test and impacts on annual energy demand were quantified. Using simulation tools, improvements are proposed, and the results are compared with examples of PH housing in other geographical areas. The annual energy demand of PH housing was 69.19% below the usual value for buildings in the Mediterranean region. Very thick thermal insulation and low values of airtightness could be applied to the envelope, which would work very well in the winter. These technique solutions could provide optimal comfort conditions with a well-designed air conditioning system in summer and low energy consumption.