We have fabricated, tested and analyzed the reliability of Pt-and RuO 2 -coated ohmic microrelays in ultra-high purity gas environments. RuO 2 -coated relays could survive 3 × 10 8 contact cycles without electrical degradation, while Pt-coated devices degraded after 10 5 cycles. Thermally actuated microrelays were fabricated using a process that employed a polysilicon surface-micromachined substructure. After releasing the devices, just a few blanket metal depositions were required to create the different coatings. This method allowed direct comparisons between different coating materials, and was enabled by a self-aligned shadow mask that provides electrical isolation between different traces. Testing was performed in a clean environment achieved through in situ ultra-high vacuum bakeouts, chamber cooling to <5 × 10 −9 Torr and chamber refill with ultra-high purity gases. The RuO 2 coatings were formed by two avenues-reactive sputtering and thermal oxidation. No significant difference in contact resistance or reliability was detected for these two deposition methods. For all coatings, post-test analysis by scanning electron microscopy and Auger electron spectroscopy indicated no difference in carbon concentration on real contact versus non-contacting areas, implying that carbon did not play a role in limiting the switches' reliability. The Pt-coated switch reliability limit was attributed to surface wear rather than to the growth of a contaminating film. For the RuO 2 switches, trace resistance was reduced by ten times using an Al underlayer, so that the total device resistance was compatible with commercial device requirements. Because RuO 2 is expected to be resistant to hydrocarbon contamination, this work shows that the RuO 2 coating provides a promising path toward achieving ultra-high reliability ohmic microswitches.