2004
DOI: 10.1016/j.polymer.2004.08.024
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Microphase separation under constraints: a molecular thermodynamic theory for polyelectrolytic amphiphilic model networks in water

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Cited by 51 publications
(46 citation statements)
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References 50 publications
(74 reference statements)
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“…For shorter I blocks, and above a certain concentration dendronlike micellar aggregates can be formed due to a loop to bridge transition and finally a three-dimensional physical network structure is obtained. A molecular thermodynamic theory, which considers various possible morphologies of the networks (spherical, cylindrical, lamellar and unimers) has been developed by Georgiou et al [22]. If an insoluble block is replaced by a soluble block, a completely different kind of micelles are formed.…”
Section: Self-assembly Of Triblock Copolymersmentioning
confidence: 99%
“…For shorter I blocks, and above a certain concentration dendronlike micellar aggregates can be formed due to a loop to bridge transition and finally a three-dimensional physical network structure is obtained. A molecular thermodynamic theory, which considers various possible morphologies of the networks (spherical, cylindrical, lamellar and unimers) has been developed by Georgiou et al [22]. If an insoluble block is replaced by a soluble block, a completely different kind of micelles are formed.…”
Section: Self-assembly Of Triblock Copolymersmentioning
confidence: 99%
“…The synthesis of conetworks composed of polymer chains of well‐defined molecular weight (MW) and composition19 requires the use of controlled polymerization techniques 20. To this end, for the past 9 years our research team has been employing such controlled methods for the preparation of APCNs of improved structure by sequential polymerization and end‐linking in one pot 21–28…”
Section: Introductionmentioning
confidence: 99%
“…More specifically, we will consider a regular network of endlinked diblock copolymers. Experimentally, the synthesis of such ideal copolymer networks is coming within reach [43], and simple phenomenological theories have been devised to predict the expected microphase separation [44,45]. A more refined SCF theory which can predict the phase behavior of such systems based on molecular parameters is thus clearly desirable.…”
mentioning
confidence: 99%