Due to the asymptotic structure of the black hole solution, there are two different thermodynamic schemes for the charged Banados–Teitelboim–Zanelli (BTZ) black hole. In one scheme, the charged BTZ black hole is super-entropic, while in the other, it is not (the reverse isoperimetric inequality is saturated). In this paper, we investigate the thermodynamic curvature of the charged BTZ black hole in different coordinate spaces. We find that in both schemes, the thermodynamic curvature is always positive, which may be related to the information of repulsive interaction between black hole molecules for the charged BTZ black hole if we accept an empirical relationship between the thermodynamic curvature and interaction of a system. More importantly, we provide a diagnosis for the discrimination of the two schemes from the point of view of the thermodynamics geometry. For the charged BTZ black hole, when the reverse isoperimetric inequality is saturated, the thermodynamic curvature of an extreme black hole tends to be infinity, while when the reverse isoperimetric inequality is violated, the thermodynamic curvature of the extreme black hole goes to a finite value.