Microstructural and electrochemical study of La0.5Li0.5TiO3

Manipulating interfacial stability of LiNi0.5Co0.3Mn0.2O2 cathode with sulfide electrolyte by nanosized LLTO coating to achieve high-performance all-solid-state lithium batterie

“…2 f), indicating the amorphous LLTO coating, which is consistent with XRD pattern of pure LLTO (Fig. S7) previously reported literature [35] . Additionally, three elements of Ni, Co and Mn are mainly distributed in the center of the material, and the Ti element is attached to the surface of material particles, revealing that a core-shell structure of LLTO@NCM532 material has been formed (Fig.…”

“…Li 0.5 La 0.5 TiO 3 sol is prepared according to the method in the previous literature [34][35][36] . Briefly, lithium nitrate (Alfa, 99%) and lanthanum nitrate hydrate (Sigma-Aldrich, 99.9%) were weighed in a glovebox based on the stoichiometric ratio of Li 0.5 La 0.5 TiO 3 , then dissolved in titanium (IV) isopropoxide (Sigma-Aldrich, 99.9%).…”

Enhanced lithium ion conductivity in lithium lanthanum titanate solid electrolyte nanowires prepared by electrospinning

“…The synthesis of these bulk powders requires multiple calcination steps at temperatures > 1250 °C and more than 24 h of annealing time [5]. For this reason, sol-gel methods have been pursued as a means to obtain LLTO solid electrolyte materials at lower calcination temperatures [6][7][8][9][10][11][12]. Additionally, sol-gel routes can realize powders with smaller particles sizes, which can form denser and more compact ceramic pellets.…”

Lithium lanthanum titanate perovskite ionic conductor: Influence of europium doping on structural and optical properties

“…La 2/3-x Li 3× TiO 3 system has been extensively studied for use in lithium batteries as electrodes, solid electrolytes and as separators in lithium-air batteries as a result of its high ion mobility, which can reach up to 10 −3 S cm −1 at room temperature [1][2][3]. Based on the work conducted by Inaguma et al [4] which reported high mobility of lithium ions in La 0.55 Li 0.35 TiO 3 composition, several mechanisms for the conduction of La 2/3-x Li 3× TiO 3 compounds have since been proposed associated mainly with structural considerations, conductivity measurements and theoretical models aiming at justifying the high ionic conductivity at room temperature [5][6][7][8][9][10][11][12][13][14].…”