Microstructure and mechanical properties of high-manganese-containing high-speed twin-roll cast Al-Mn-Si alloy strips and their cold-rolled sheets

Abstract

Al-Mn based alloys with high-manganese content are expected to have improved mechanical properties due to solid solution hardening and/or dispersion hardening. However, the increase of Mn solubility of the alloy is difficult by using the conventional DC casting. In order to solve this problem, in the present study, we focused on the twin-roll casting method which is characterized by high cooling rates. Several kinds of high Mn-containing Al-Mn-Si alloy strips were fabricated by using a vertical-type high-speed twin-roll caster equipped with a pair of water-cooled copper rolls. Direct temperature measurement of the liquid melt during the casting was also performed. The alloy strips of various compositions containing up to 4 Mn and 2 Si (wt%) were successfully obtained. By observing the microstructure of the cross section of the strip, we found the characteristic solidified structure. The solidified structure consisted of three layers. Two solidified shells with a columnar dendrite structure grew from the roll surfaces toward the strip center. In the mid-thickness region, the band structure consisting of equiaxed dendrites and globular grains was observed between the solidified shells. Very fine primary particles were observed in the matrix near the strip surface, while, relatively coarse particles with blocky and needle-like shape were observed in the central band of the as-cast strip. The electric conductivity measurement was performed for the as-cast strips. Mn solubility in Al matrix was estimated from the obtained values. The estimated Mn solubility in the Al-2Mn-xSi strips was between 1.5 ~ 1.8wt% Mn. It was over 1.43wt%Mn for the Al-4Mn-xSi strips. We found that the Mn solubility of the as-cast strips was considerably high. The strips were cold-rolled to the sheets and then annealed at various conditions. They were subjected to the tensile tests, and the effects of solid solution hardening and dispersion hardening are discussed.

Effect of Large Particles in Central Band of Al–4%Mn–1%Si High-Speed Twin-Roll Cast Strip on Elongation of Cold-Rolled and Annealed Sheets

“…The detail of the estimation was reported in the previous report. 16) The EC measurement was carried out on the polished surfaces of the strips.…”

“…These results are consistent with the previous report. 16) Although the strength increases, the low elongation with considerable variations may reduce the potential of the 4M1S sheet in high strength applications.…”

“…High-Mn containing alloys have been successfully produced by a high-speed twin-roll casting (HSTRC) method. 16) HSTRC is a near-net-shape casting method to fabricate thin aluminum alloy strips from a molten alloy at a high speed (60120 m/min). 1720) The capital investment and operating cost for HSTRC are lower than conventional DC casting because intermediate manufacturing processes (i.e., homogenization, hot-rolling, and cold-rolling processes) are unnecessary.…”

“…A report found that the mechanical properties of the sheets fabricated from the cast strips are superior to those of commercial alloys. 16) However, increasing the Mn concentration to 4 mass% results in a low and highly scattered elongation. Although the strength is improved, a low elongation with large variations may reduce the potential applications of high Mn-containing sheets.…”