Al2O3/TiN/graphene ceramic tool materials were prepared by spark plasma sintering technology and the strengthening and toughening mechanisms were studied. The influence of monolayer graphene content on the mechanical properties and microstructure of the composite material were analyzed and the strengthening and toughening mechanisms were researched. The results showed that with an addition of .5 vol.% graphene the mechanical properties of the material reached the best. The bending strength, hardness, and fracture toughness were 624 MPa, 23.24 GPa, and 6.53 MPa·m1/2, respectively. Graphene existed in the forms of few‐layer and multilayer. The toughening mechanism of few‐layer graphene was mainly graphene breaking, and that of multilayer graphene included graphene breaking and pulling‐out. Graphene could contribute to the uniform growth of grains due to the excellent electrical conductivity and the high thermal conductivity. The addition of nano‐TiN introduced many endocrystalline structures and graphene promoted this phenomenon. Micro‐TiN grains made the crack extension show a combination of transgranular fracture, intergranular fracture, crack bridging, and crack deflection, while graphene introduced weak grain interfaces and made the crack appear more branches. The layered graphene made the material fracture change from two‐dimension to three‐dimension.