The purpose of this study is to discuss the development of dendrite δ-ferrite and the precipitation behavior of σ phase in the overlapping heat-affected zones, or the fusion zones, during the multipass dissimilar stainless steels welding process. The color metallographic and color separation techniques were used to clearly identify the δ, σ, and γ phases. The experimental results indicated that the grain refinement was very obvious in the second and third pass fusion zones (304-1 and 304-2) when the welding pass was increased from 1 to 3. This refining phenomenon was attributed to the higher cooling rate and the degree of supercooling. The δ phase precipitated in the secondary and the tertiary dendrite arms of the δ-ferrite and it was able to grow on the dendrite arms along the [111] crystallographic in a 45 o angle. The σ phase was also able to form stably after the phase decomposition of δ-ferrite into globular and lacy morphologies.