Making alloys of Mg and Li is quite a task as their individual melting temperatures are vastly different. However, it is thought paid off considering their extreme lightness. Basically, low melting temperature Li could cause Mg-Li alloys' microstructures change at room temperature (R.T.). Recrystallization and aging of Li-rich solid solution phase () can proceed under R.T. Previously, R.T. aging phenomenon was mentioned without in-depth analysis. This paper fills up the blank by working on Mg-11.2%Li-0.95%Al-0.43%Zn (mass%), mainly due to the TEM work brought in. With this apparatus for analysis, a transition precipitate (tentatively called pre-phase) is revealed. This preprecipitation is responsible for the distinctive strengthening in the initial stage of R.T. aging. However, it is unstable and subsequently transforms to or phase. Both of these later precipitates are little effective in producing aging strengthening.