Microwave Dielectric behaviour of ketones in solution state at a constant temperature

Ganesh, T.; Sylvester, M. Maria; Bhuvaneswari, S.; Jeevanantham, P; Kumar, Sanjay

doi:10.9790/4861-06225963

Cited by 1 publication

(1 citation statement)

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“…17 From Table 3 also shows that the observed values of intramolecular rotations are significantly higher than overall molecular rotation and this significant difference in the values of τ 1 and τ 2 represents the existence of more than one mechanism in the solution which shows that an additional intramolecular relaxation process exist along with the overall relaxation process in solution. 18 It also indicates the dominance of intramolecular rotations over intermolecular rotations in solution.…”

Section: Resultsmentioning

confidence: 99%

Microwave Dielectric Measurements of 4-Nitroacetanilide at Different Temperatures in Carbon Tetrachloride Solution

Manro¹,

Jain²

2018

Orient. J. Chem

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The dielectric properties of 4-Nitroacetanilide have been discussed at four different temperatures in the dilute solution of carbon tetrachloride at a fixed frequency of 9.27GHz. The values of dielectric constant (εʹ), dielectric loss (εʺ), permittivity at an optical frequency (ε∞) and permittivity at a static frequency (ε0) are measured at different temperatures and mole fractions. The values of these dielectric parameters are used to calculate the values of relaxation time for overall molecular rotation (τ1), relaxation time for intramolecular rotation (τ2), most probable relaxation time (τ0) and dipole moment (μ) at different temperatures. In the present investigation we have found higher values of τ2 which indicate the existence of more than one relaxation process in the solution. The values of energy activation parameters for dielectric relaxation process (∆Fε, ∆Hε and ∆Sε) and viscous flow process (∆Fη, ∆Hη and ∆Sη) are also determined and compared for 4-Nitroacetanilide with carbon tetrachloride at different temperatures. It is observed that we may treat both the process as a rate process.

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Section: Resultsmentioning

confidence: 99%