Two important molecular parameters, namely, the dielectric relaxation time and electric dipole moment are highly useful in having insight into the molecular structure, size, shape, apart from the inter-and intra-molecular forces, etc. With these in view dielectric measurements in benzene at room temperature on the pure samples of o-ethyl phenol, 2-n-butylphenol, 4-n-butylphenol, 2,6-dimethoxyphenol and 3,4-difluorophenol were carried out at a frequency of 9.98 GHz by employing concentration variation method. Similar measurements, on a single weight fraction of each of them at 9.98 GHz and also at 8.74 GHz are carried out. Measurements on a single weight fraction in benzene of each of the liquid crystal samples, namely, EPCP.car (Butyl-p-(p-ethoxy phenoxy corbonyl)-phenyl carbonate), PPPB (p-pentylphenyl-p-propyl benzonate), EPAP.Hp (p-(p-ethoxyphenyl azo) phenyl heptenate) and EPAP. Und (p-(p-ethoxyphenyl azo) phenyl undecylenate were also carried out at the said two frequencies. Using the obtained values of " 0 , " 00 relaxation time and dipole moment were determined using different methods. The obtained results are compared with earlier results wherever available.