To simultaneously meet the demands of small size for
easy transportation
and injection as well as temperature and salinity resistance, 2-acrylamide-2-methylpropanesulfonic
acid (AMPS)/AM@SiO2 microgel particles were synthesized
to achieve a good performance for the in-depth profile control treatment.
The characteristic functional group, mechanical property, and enhanced
oil recovery (EOR) performance were comprehensively evaluated by Fourier
infrared spectrometer, nanoindentation apparatus, and sand-packed
tubes with different permeability conditions. AMPS contains active
double bonds and sulfonic acid groups, which could enhance the temperature
and salinity resistance of gel systems. Therefore, the AMPS/AM and
AMPS/AM@SiO2 microgel particles have remarkable temperature
and salinity tolerance and can be used at a high temperature (130
°C) and high salinity conditions (200,000 mg/L). The mechanical
energy can be dissipated effectively by adding 1.0 wt % nano-SiO2 which could significantly improve the compression strength
and elastic modulus. The elastic moduli of the AMPS/AM@SiO2 microgel particles (1500 mg/L) are 17.36 MPa, which is much higher
than that of AMPS/AM microgel particles (10.44 MPa). This effect can
improve the performance of the antierosion and compression deformation
of the AMPS/AM@SiO2 microgel particles. The AMPS/AM@SiO2 microgel particles not only have good plugging performance
and antierosion stability that can divert the subsequent injected
fluid to lower permeable zones but also can achieve an in-depth secondary
plugging effect through compression deformation and remigration. The
performance of profile control and oil displacement of the AMPS/AM@SiO2 microgel particles has been verified from parallel sand-packed
tubes simulating strong heterogeneous reservoirs. Compared with water
flooding, the total oil recovery was increased by 22.8% after the
injection of 0.5 PV AMPS/AM@SiO2 microgel particles, which
is higher than that of AMPS/AM microgel particles (16.4%). This work
not only provides a potential agent, i.e., AMPS/AM@SiO2 microgel particle, for in-depth profile control in high temperature
and high salinity offshore oilfields but also helps for a better understanding
of the mechanism of in-depth profile control and EOR for microgel
particles.