Fr and 201 At, respectively, using γ -ray and conversion electron spectroscopy at the CERN isotope separator on-line (ISOLDE) facility. The EC/β + branch from 205 Fr was measured to be 1.5(2)%. The excited states of the daughter nuclei are understood in terms of the odd nucleon coupling to the neighboring even-even core. The neutron single-particle energies of the p 3/2 orbital relative to the f 5/2 ground state in 205 Rn, and the f 5/2 orbital relative to the p 3/2 ground state in 201 Po, were determined to be 31.4(2) and 5.7(3) keV, respectively. We tentatively identify a − levels is also discussed.