In this paper, we consider estimators for an additive functional of φ, which is defined as θ(P ; φ) = k i=1 φ(pi), from n i.i.d. random samples drawn from a discrete distribution P = (p1, ..., p k ) with alphabet size k. We propose a minimax optimal estimator for the estimation problem of the additive functional. We reveal that the minimax optimal rate is characterized by the divergence speed of the fourth derivative of φ if the divergence speed is high. As a result, we show there is no consistent estimator if the divergence speed of the fourth derivative of φ is larger than p −4 . Furthermore, if the divergence speed of the fourth derivative of φ is p 4−α for α ∈ (0, 1), the minimax optimal rate is obtained within a universal multiplicative constant as n .