In this paper, we have obtained an analytical solution to the problem of unsteady free convection and mass transfer flow of an incompressible fluid through a vertical channel in the presence of Dufour effect (or diffusion thermo). The bounding plates are assumed to have ramped wall temperature as well as specie concentration. The mathematical model responsible for the physical situation is presented in dimensionless form and solved analytically using the powerful Laplace Transform Technique (LTT) under relevant initial and boundary conditions. In order to cross check the accuracy of the analytical results, numerical solutions are obtained using PDEPE solver in MATLAB. The expressions for temperature, concentration, and velocity are obtained. The effects of Dufour parameter, Prandtl number (Pr), Schmidt number (Sc), and dimensionless time are described during the course of these discussions. The temperature, concentration, and velocity profiles are graphically presented for some realistic values of Pr = 0.025, 0.71, 7.0, 11.62, 100.0 and Sc = 0.22, 0.60, 1.00, 2.62, while the values of all other parameters are arbitrarily taken.Physics 2019, 1 112 unsteady magnetohydrodynamics natural convection flow through a porous medium, with ramped boundary conditions, over an infinite inclined wall in the presence of thermal radiation. Authors in [20] showed how heat and mass transfer were affected, by introducing a perfectly thin conducting baffle in a vertical channel, filled with electrically conducting and chemically reacting fluid. After inserting the baffle, the fluid is concentrated in each stream with different chemically reacting agents. The basic governing equations were solved by perturbation method and also by Differential Transformation Method (DTM). The effects of Joule-heating, chemical reactions, and thermal radiation on unsteady magnetohydrodynamic (MHD) natural convection, from a heated vertical porous plate in a micropolar fluid, were analyzed by [21]. The partial differential equations, governing the flow and heat and mass transfer, were solved numerically using an implicit finite-difference scheme. The case corresponding to vanishing of the anti-symmetric part of the stress tensor, that represents weak concentrations, was considered. Authors in [22] studied the steady laminar magneto-hydrodynamic thermosolutal Marangoni convection, in the presence of a uniform applied magnetic field, in the boundary layer approximation. They assumed that the surface tension varies linearly with both the temperature and concentration, and that the interface temperature and concentration are quadratic functions of the interface arc length x. Exact analytical solutions for the velocity, temperature, and concentration boundary layers were obtained.Two important phenomena in heat and mass transfer processes are Dufour and Soret effects. Dufour effect (also diffusion-thermo) is the transfer of heat, generated by a concentration gradient, while Soret effect (also thermal diffusion) is the mass transfer generated by temperature ...