MNDO studies of proton affinity as a probe of electronic structure. 2. Boranes and carboranes

DeKock, Roger L.; Jasperse, Craig P.

doi:10.1021/ic00168a005

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H Unsupported 3c-2e Bonds1

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1984

1999

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Cited by 22 publications

(2 citation statements)

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“…The isoelectronic C2H7+ ion also is calculated to have a bent structure (36). Angular 3c-2e bonds are predicted to occur upon protonation of many boranes and carboranes (37).…”

Section: H Unsupported 3c-2e Bondsmentioning

confidence: 99%

The three-center, two-electron chemical bond

DeKock¹,

Bosma²

1988

J. Chem. Educ.

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“…The isoelectronic C2H7+ ion also is calculated to have a bent structure (36). Angular 3c-2e bonds are predicted to occur upon protonation of many boranes and carboranes (37).…”

Section: H Unsupported 3c-2e Bondsmentioning

confidence: 99%

The three-center, two-electron chemical bond

DeKock¹,

Bosma²

1988

J. Chem. Educ.

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“…Reflux of 76 with ethanol in the presence of di-chloromethane245 afforded a product with an expanded 10-membered intercage ring, 7,7':8,8,-(SCH2S)2-[7,8-C2B9H10][7/,8/-C2B9H10] (simplified structure 78). The Bo rt"CHrs-c 78 same authors246,247 have also built up exomacropolycyclic rings on the 74 moiety from a general reaction involving 1,2-(HS)2-1,2-C2B10H10 as a starting material at high dilution of the reagents:(HS)2C2B10H10 + 3EtOH + 30H-+ C1CH2(CH20CH2)"CH2C1 -2CT + B(OEt)3 + [CH2(CH2OCH2)"CH2S2C2B9H10]-+ 3H20 + H2(31)…”

mentioning

confidence: 99%

Carboranes other than C2B10H12

Štı́br¹

1992

Chem. Rev.

163

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The Hexahydro-closo-hexaborate Dianion [B6H6]2– and Its Derivatives

Preetz

Peters

1999

Eur. J. Inorg. Chem.

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[B6H6]2– as the smallest known hydro‐closo‐borate is only moderately stable, and therefore its reaction chemistry remained unexplored for quite a long time. Since the mid 1980s some progress has been made in this field, and a considerable number of derivatives has been prepared. The provided structural and spectroscopic data together with the results of more sophisticated theoretical investigations by high level ab initio methods are a good basis for a systematic review on this class of compounds, and may encourage further synthetic and theoretical work. This is the aim of the present article giving a comprehensive survey up to the beginning of 1999.

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MNDO studies of proton affinity as a probe of electronic structure. 2. Boranes and carboranes

Cited by 22 publications

References 2 publications

The three-center, two-electron chemical bond

The three-center, two-electron chemical bond

Carboranes other than C2B10H12

The Hexahydro-closo-hexaborate Dianion [B6H6]2– and Its Derivatives

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