MnO₂ Nanowires Decorated with Au Nanoparticles for Plasmon-Enhanced Electrocatalytic Detection of H₂O₂

Abstract

MnO2 is a cheap and versatile material, being able to act as a catalyst for different electrochemical reactions. The addition of small amounts of Au nanoparticles (NPs) enables the possibility to explore the localized surface plasmon resonance (LSPR) effect to improve the photocatalytic properties of MnO2. The LSPR effect can accelerate several reactions under visible light irradiation, improving the charge separation and light harvesting properties of semiconductors. Here, by employing MnO2 nanowires decorated with Au NPs (MnO2–Au), we demonstrated that MnO2 catalytic activity can be greatly improved by the LSPR in a hybrid system. The catalytic properties of the semiconductor were demonstrated for the H2O2 oxidation as a model reaction. A clear increase in the current of H2O2 oxidation was verified for gold decorated nanowires under visible light irradiation, with an increase of 116% in the sensitivity compared with dark conditions. Mechanistic analysis indicates that the increased performance was related to a more efficient charge separation by plasmonic generated hot electrons and holes. Moreover, we demonstrated that the thermal effect had no significant contribution to the increase in activity observed, as it was verified no expressive increase in temperature under light irradiation with a thermal camera. We believe the results reported herein provide an approach to achieve improved light harvesting and performance in the visible range of the spectrum for semiconductors, inspiring the use of plasmonic heterostructures toward electrocatalysis.

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“…These results are even better than those of composites containing Au NPs and enhanced with the LSPR effect in the literature (Table 2). [44][45][46][47][48] In order to better use the CZIF/Au, the catalytic stability of H 2 O 2 was tested at 655 nm. As shown in Fig.…”

Multifunctional and multimodality theranostic nanomedicine for enhanced phototherapy

“…It has been found that MnO 2 nanostructures could catalyze degradation of H 2 O 2 into water and O 2 in a tumor acidic environment, so as to alleviate the tumor hypoxic microenvironment. [18][19][20] Meanwhile, MnO 2 nanostructures can also undergo a redox reaction with GSH to yield Mn 2+ and glutathione disulfide (GSSG), thus scavenging GSH in cancer cells. 21 The generated Mn 2+ ions could significantly enhance T1-magnetic resonance (MR) imaging contrast for tumor-specific imaging.…”