Mo–V–Nb Oxide Catalysts for the Partial Oxidation of Ethane

A self-redox pure-phase M1 MoVNbTeO /CeO2 nanocomposite as a highly active catalyst for oxidative dehydrogenation of ethane

“…4, one broad peak in the range 400-700°C is observed for each catalyst, due to the reduction of Mo 6+ , V 5+ , Te 6+ , and Ce 4+ species [53]. It is known that Mo 6+ and V 5+ are reduced more easily in mixed metal oxide solid solution than in pure MoO 3 and V 2 O 5 [54]. The M1-Ce-SM catalyst exhibits the greatest reducibility of lattice oxygen, whereas the M1 catalyst is the most difficult sample to reduce.…”

Ammoxidation of ethane on V-Mo-Nb oxide catalysts<span lang=EN-US style='font-size:10.0pt;mso-ansi-language:EN-US'>

“…Among the oxide vanadium-molybdenum catalysts modified by different additives, the V-Mo-Nb samples [1][2][3][4][5][6] hold the greatest promise for lowtemperature oxidation of ethane into ethylene and acetic acid. In the literature, opinions differ on the nature of an active component of the above catalysts.…”

Phase-pure M1 MoVNbTeO x catalysts with tunable particle size for oxidative dehydrogenation of ethane

“…6, one broad peak in the range of 400-700 • C is observed for each catalyst, due to the reduction of Mo 6+ , V 5+ and Te 6+ species [67]. It is known that Mo 6+ and V 5+ are reduced more easily in mixed metal oxide solid solution than in pure MoO 3 and V 2 O 5 [68]. Although it is difficult to distinguish the corresponding peak for each cation in the mixed metal oxide due to the complex reduc- tion reaction, the broad peak can be resolved to three peaks with the same Lorentzian-Gaussian of 20% by de-convolution.…”