MOCVD of Silver Thin Films from the (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato)-silver[bis(trimethylsilyl)acetylene] Complex

Chi, Kai-Ming; Yong, Lu

doi:10.1002/1521-3862(200105)7:3<117::aid-cvde117>3.0.co;2-7

Cited by 46 publications

(22 citation statements)

References 3 publications

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“…[20] In addition, the bond distances Ag1-C1 (2.2918(17) Å) and Ag1-C2 (2.4111(16) Å) in 2 are considerably longer when compared to the reported Ag(I)-alkyne complexes. [18][19][20][21] These observations suggest a weak interaction between Ag(I) cation and the enyne substrate.…”

Section: Resultsmentioning

confidence: 99%

A simple Ag(I)-enyne cation

Sanguramath

Townsend

Russell

2016

Journal of Organometallic Chemistry

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General rightsThis document is made available in accordance with publisher policies. Please cite only the published version using the reference above. 9190401, Israel AbstractA simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.

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Section: Resultsmentioning

confidence: 99%

A simple Ag(I)-enyne cation

Sanguramath

Townsend

Russell

2016

Journal of Organometallic Chemistry

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“…where L were tertiary phosphines (PPh 3 ), 2,5,8,11,14pentaoxapentadecane or bis(trimethylsilyl)-acetylene) or carboxylates (Ag(O 2 C-L)). 9,11,15 Apart from the low solubility of these precursors in alcohol solvents, other issues such as low volatility or the high toxicity of the ligands have been also reported. 14,16,20 In addition, some of the ligands are rather expensive, contributing to a higher price of the final Ag precursor.…”

Section: Introductionmentioning

confidence: 99%

Deposition of metallic silver coatings by Aerosol Assisted MOCVD using two new silver β-diketonate adduct metalorganic precursors

et al. 2017

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This work reports two new silver metalorganic precursors for the chemical vapor deposition of Ag metallic coatings. Both precursors are based on β-diketonate adducts, namely, Ag(hfac)(L) (H-hfac = 1,1,1,5,5,5-hexafluoro-2,4-pentanedione), where L is 1,10-phenanthroline (phen) or 2,5,8,11-tetraoxadodecane (triglyme). Using these ligands, the designed precursors have better solubility in alcoholic solvents and are less toxic and costly than previously reported ones. The new precursors have been characterized and their crystallographic structure solved. With the new triglyme precursor, [Ag(triglyme)][Ag(hfac)], pure metallic Ag coatings made of Ag nanoparticles about 20 nm in diameter were succesfully deposited on glass and Si substrates using Aerosol Assisted Metalorganic CVD (AA-CVD).

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“…A number of them have been synthesized, characterized and applied, including perfluorinated carboxylate silver(I) [1], perfluorinated carboxylate trimethylphosphine silver(I) [2,3], (b-diketanato) silver(I) bis(trimethylsilyl)acetylene [4], silver(I) alkanoates [5,6], bis-triphenylphosphine-silver(I) stearate [7], silver(I) b-diketiminate complexes [8], crown ether silver(I) carboxylate complex [9], and so on.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

Cao

Liu

et al. 2012

J Chem Crystallogr

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A novel silver-containing compound bisbenzylamino-silver(I) benzylcarbamate with the molecular formula of C 22 H 26 N 3 O 2 Ag and structural formula of C 6 H 5 CH 2 NHCOOAg(NH 2 CH 2 C 6 H 5 ) 2 is synthesized by the reaction of benzylamonium benzylcarbamate and silver oxide. It crystallizes in triclinic crystal system and P-1 space group with a = 5.2006(5) Å , b = 14.6298(15) Å , c = 14.7246(15) Å , a = 68.729(2)°, b = 83.507(2)°, c = 85.412(2)°, and Z = 2. In the crystal, all of the silver atoms are two-coordinate, i.e., one silver atom symmetrically chelates with the two amino groups in two benzylamine molecules, while all the carboxylate groups only act as charge balancers. In addition, the crystal contains a large quantity of hydrogen bonds sustaining the stability of three-dimensional structure.

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MOCVD of Silver Thin Films from the (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato)-silver[bis(trimethylsilyl)acetylene] Complex

Cited by 46 publications

References 3 publications

A simple Ag(I)-enyne cation

A simple Ag(I)-enyne cation

Deposition of metallic silver coatings by Aerosol Assisted MOCVD using two new silver β-diketonate adduct metalorganic precursors

Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

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