The room-temperature magnetic properties of core–shell
iron–iron
oxide nanoclusters (NCs) synthesized by a cluster deposition system
were investigated, and their dependence on mean cluster size is discussed.
In this study, the surface/boundary spins of clusters were not frozen
and were thermally activated during the measurements. The intercluster
interactions between clusters and intracluster interactions between
the iron core (ferromagnetic) and iron oxide shell (ferrimagnetic)
were investigated by field-dependent isothermal remanent magnetization
and dc demagnetization measurements at room temperature. The Henkel
and ΔM plots support the existence of dipolar
intercluster interactions that become stronger with the growth of
the clusters. The derivative of the initial magnetization curve implies
that smaller clusters require lower fields and less time than larger
ones to overcome various energy barriers before saturating the moments
along the field direction. Coercive field and magnetization were also
correlated with the interaction parameters. To compare the room-temperature
magnetic results, one system was studied at low temperature, where
exchange coupling at the interface between the oxide and metallic
phases was observed through bias effect and anisotropy enhancement.