Modeling of Methane Solubility in Heavy n-Paraffins.

VLE predictions with the Peng–Robinson equation of state and temperature dependent kij calculated through a group contribution method

“…The values we have used in this study are T C = 805 K, P C = 10.5 bar and ω = 1.05. A comparison of prediction with the PPR78 model and experiment [191][192][193] is illustrated in Fig. 7.…”

“…The used parameters are thus: T C = 822.81 K, P C = 5.98 bar and ω = 1.292. For this system, five (P, T, x, y) data points were measured at five different temperatures by Huang et al [193]. As shown in Fig.…”

Modeling the phase equilibria of asymmetric hydrocarbon mixtures using molecular simulation and equations of state

“…Pressure – composition VLE for the CH 4 ‐ n ‐C 24 H 50 mixture at various temperatures; (a) T = 330 K, (b) T = 350 K, (c) T = 374.05 K, (d) T = 523.15 K. Experimental data are represented by black data points and GEMC simulation data by red squares. [Color figure can be viewed at wileyonlinelibrary.com]…”

Development and application of computational algorithms and thermodynamic models for multiphase, multicomponent chemical systems

“…To Experimental data [208][209][210] are represented by black data points and GEMC simulation data by red squares.…”

“…Figure 7.1: Pressure -composition VLE for the CH 4 -n-C 24 H 50 mixture at various temperatures; (a) T= 330 K, (b) T= 350 K, (c) T= 374.05 K, (d) T= 523.15 K.Experimental data[208][209][210] are represented by black data points and GEMC simulation data by red squares.…”