Modeling phase behavior of carbon dioxide with aromatic solvents

Vapor–liquid equilibria at elevated pressures of binary mixtures of carbon dioxide with methyl salicylate, eugenol, and diethyl phthalate

“…8. It is indicated by Jan and Tsai [8] that the methyl group in the benzene ring increases the solubility of carbon dioxide and the substituent hydroxy group shows the opposite effect. According to this explanation, we observe that at a given pressure carbon dioxide has the largest solubility in diethyl phthalate, and the least solubility in methyl salicylate.…”

Transitiometry: PVT – Scanning Calorimetry for the Simultaneous Determination of Thermal and Mechanical Properties

“…At a carbon dioxide pressure of five MPa the melting point of naphthalene is 343.81 K and the solubility of carbon dioxide is 23 mol-%. The Px behavior predicted with PSRK at 373.15 K is compared with vapor-liquid-equilibrium data measured by Jan and Tsai [7] at the same temperature and plotted in Fig. 8.…”

Measurement and Correlation of Vapor−Liquid Equilibria for Asymmetric Mixtures of Helium and Polar Compounds

“…The saturated vapor compositions of 1-decanol at 353.45 K are too small to be determined accurately, for which dashed lines are marked in Table . The thermodynamic consistency test for these P − T − x i − y i data was performed with the method as proposed by Chueh et al The Gibbs−Duhem equation used in the test is given by where The procedure of calculation is similar to that described by Jan and Tsai . Table lists the results of the consistency test over the entire experimental composition range ( x 1 ), indicating that the deviations between the right-hand side (RHS) and the left-hand side (LHS) of eq 1 is smaller than 3.2% for helium + 1-hexanol and 1% for the other two binary systems.…”