Coal-like materials have been widely used to simulate low-rank coalbed methane (CBM) reservoirs to develop fracturing stimulation technology since the transportation and preparation of low-rank coal produce easily secondary damages, causing large dispersion of test results. However, the coal particle sizes have a significant effect on the performance of coal-like materials among many factors. Hence, to accurately simulate lowrank CBM reservoirs for promoting the development of reservoir stimulation technologies, cement, gypsum, pulverized coal, and sand were selected as similar materials to make coal-like samples with different coal particle sizes to study the influence law of coal particle size on the mechanics, pore structure, and permeability of samples. The ultrasonic wave velocity, dynamic parameters, uniaxial compressive strength, elastic modulus, and uniaxial tensile strength of samples increased with increasing coal particle size in the range of 0−2 mm. However, these parameters suddenly decreased when the coal particle size increased to 2−3 mm. The porosity and permeability of the samples exhibited an opposite trend compared to the above parameters. The fracture occurred in cementing materials, and the crack extension direction was affected by the coal particle sizes. The fracture complexity of the coal-like samples decreased with increasing particle size under uniaxial compressive testing. The failure mode was mainly a tensile failure, supplemented by shear failure. The coal-like materials can well meet the performance requirements of low-rank CBM reservoirs.