Modelling across Multiple Scales to Design Biopolymer Membranes for Sustainable Gas Separations: 1—Atomistic Approach

Three-dimensional printing is widely used for manufacturing a variety of functional components. However, the 3D printing machine substantially limits the size of the functional components. Rotary friction welding (RFW) is a possible solution to this problem. In addition, there is a notable scarcity of research directed toward the domain knowledge of RFW involving dissimilar polymer rods containing metal powder. In this study, two welding specimens fabricated by polylactic acid (PLA)-containing copper powder and PLA-containing aluminum powder were joined using a turning machine. After RFW, a bending test and a Shore A surface hardness test were performed to investigate the weld quality. It was found that the bending strength of the welded parts fabricated by RFW of PLA and PLA-containing Al powder rods can be enhanced by about 57.5% when the welded part is placed at 45 °C. Surface hardness test results showed that the surface hardness of the weld interface is better than that of the 3D printed parts, and the average surface hardness of the weld interface from RFW of PLA and PLA is the highest. The surface hardness of the weld joint is about 3% higher than that of the base material. The surface hardness of the heat-affected zone is about 3% lower than that of the base material. The average peak temperature of the welded joint is the highest in the RFW of PLA-containing Al powder and PLA-containing Al powder rods. The average peak temperature of the weld joint can be as high as 160 °C. The average peak temperature of the welded joint is the highest in the RFW of PLA-containing Cu powder and PLA-containing Cu powder rods. The average peak temperature of the welded joint can be as high as 144 °C. A technical database was built for the selection of ambient temperatures used for the RFW of dissimilar polymer rods containing metal powder and three base materials.

Section: Introductionmentioning

confidence: 99%

Rotary Friction Welding of Dissimilar Polymer Rods Containing Metal Powder

Kuo,

Chen,

Huang

2023

“…However, few studies focus on the fatigue life of ABS/PC polymer rods jointed via RFW. According to practical experience, the welded parts’ reliability [ 21 , 22 ] is related to the fatigue life [ 23 ]. The main objective of this study was to investigate the fatigue life [ 24 ] of the polymer rods with five different cyclic loads.…”

Section: Introductionmentioning

confidence: 99%

Fatigue Behavior of Rotary Friction Welding of Acrylonitrile Butadiene Styrene and Polycarbonate Dissimilar Materials

Kuo

Gurumurthy

Hunag³

2023

Understanding the fatigue behaviors of weld joints is significant in engineering practice. Rotary friction welding (RFW) can join the additively manufactured polymer components. Until now, no research has focused on the fatigue behavior of polymer components jointed via RFW. This study investigates the fatigue life of ABS/PC dissimilar components fabricated via RFW and proposes the fatigue mechanism based on the failure structure. This work uses five different cyclic loads and rotational speeds to investigate the fatigue life. The fatigue life of the RFW of ABS/PC dissimilar rods is better compared with the pure ABS and pure PC specimens due to weld and integrity microstructural changes resulting from the combination of ABS and PC materials. The number of cycles until the rupture of RFW of ABS/PC dissimilar components (y) can be determined by the cyclic load (x) according to the prediction equation of y = −838.25x2 − 2035.8x + 67,262. The fatigue life of the RFW of ABS/PC dissimilar components increase with the increased rotational speed. The number of cycles until rupture (y) can be determined by the different rotational speeds (x) according to the prediction equation of y = 315.21x2 + 2710.4x + 32,124.

Modelling Across Multiple Scales to Design Biopolymer Membranes for Sustainable Gas Separations: 2-Multiscale Approach

Papchenko,

Ricci,

De Angelis

2024

The majority of materials used for membrane-based separation of gas mixtures are non-renewable and non-biodegradable, and the assessment of alternative bio-based polymers requires expensive and time-consuming experimental campaigns. This effort can be reduced by adopting suitable modelling approaches. In this series of works, we propose various modelling approaches to assess the CO2/CH4 separation performance of eight different copolymers of 3-hydroxybutyrate and 3-hydroxyvalerate (PHBV) using a limited amount of experimental data for model calibration. In part 1, we adopted a fully atomistic approach based on Molecular Dynamics (MD), while, in this work, we propose a multiscale methodology where a molecular description of the polymers is bridged to a macroscopic prediction of its gas sorption behaviour. PHBV structures were simulated using MD to obtain pressure–volume–temperature data, which were used to parametrise the Sanchez–Lacombe Equation of State. This, in turn, allows for the evaluation of the CO2 and CH4 solubility in the copolymers at various pressures and compositions with little computational effort, enabling the estimate of the sorption-based selectivity. The gas separation performance obtained with this multiscale technique was compared to results obtained with a fully atomistic model and experimental data. The solubility–selectivity for the CO2/CH4 mixture is in reasonable agreement between the two models and the experimental data. The multiscale method presented is a time-efficient alternative to fully atomistic methods and detailed experimental campaigns and can accelerate the introduction of renewable materials in different applications.