This paper investigates the risk assessment method of electrical fires of high-rise buildings based on hybrid decision models considering asymmetric proximity. Based on the occurrence mechanism of electrical fires in high-rise buildings, a four-level evaluation index system considering the disaster causing body, fire site environment, affected body, and fire driving factors is established based on FP growth mining association rules, and the risk grade is divided further. An improved DEMATEL+ANP index weight assignment method for balancing the interaction relationship between indexes is proposed, and a hybrid decision model for electrical fire risk assessment in high-rise buildings, taking further account of asymmetric proximity and improved evidence cloud theory. Combined with specific examples, the effectiveness of the proposed building electrical fire risk assessment method is verified. This method can better balance each risk evaluation index, fully considering the fuzziness and randomness in the electrical fire risk assessment of high-rise buildings, and improve the accuracy and applicability of electrical fire risk assessment.