Modelling and simulation of monopropellant hydrazine thrusters for spacecraft position control

Schulz‐Ekloff, G.; Deppner, Heinz‐Günter

doi:10.1002/ceat.270120161

Cited by 8 publications

(3 citation statements)

References 7 publications

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“…The outstanding properties of Shell 405 catalysts are presumably due to a more open structure [85] or to the presence of a high fraction of η-alumina crystals (size ca. Ir crystals display an average size of around 2 nm (190 m 2 g −1 -Ir for the fresh catalyst) and show an epitaxial growth on the support with (110) orientation, which increases with firing time [36,86]. The dense crystals prevent penetration of hydrazine into the interior of the pellets, and decrease the generation of catalyst fines via break-up processes from internal overpressure [36].…”

Section: A Shell 405 Catalyst (Usa)mentioning

confidence: 99%

“…Oxidation of 1 leads to the formation of monodentate diazene ligand which can disproportionate into nitrogen and hydrazine. A modeling and simulation of a thruster application is described [86]: the catalyst must have high activity, high thermal conductivity, low thermal expansion, high thermal stability, high resistance to thermal shock, and good mechanical strength. Complexes of amides (M − NH 2 ), imides (M=NH) and nitrides [Cl 2 Os≡N] 2− are also well known in organometallic chemistry.…”

Section: Homogeneous Catalysis and Coordination Chemistry Of Hydrazinementioning

confidence: 99%

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Catalytic Decomposition of Energetic Compounds: Gas Generators and Propulsion1A list of abbreviations/acronyms used in the text is provided at the end of the chpater

Batonneau

Kappenstein

Keim

2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction Energetic Compounds Propellants Gas generators Explosive Materials Ignition systems Scope of the Chapter, and Literature Data Units Some Propulsion Elements A Short Introduction to Propulsion Theory Comparison of Propulsion Types and Propellants Propulsion System Types Propellants Advantages of Catalytic Propulsion A Brief History of Rocketry and Catalytic Propulsion The Current Supremacy of Hydrazine Introduction Catalysts Heterogeneous Catalysis: General Studies Mechanistic Considerations A Literature Overview B Thermodynamic Data C Isotope‐Related Studies D Single‐Crystal Studies E Catalytic Cycle Proposals Iridium‐Based Industrial Catalysts A Shell 405 Catalyst ( USA ) B K ali C hemie KC 12 GA Catalyst ( G ermany) C C nesro Catalyst ( F rance) D GIPKh Catalysts (former USSR ) New Hydrazine Decomposition Catalysts Homogeneous Catalysis and Coordination Chemistry of Hydrazine Applications of Hydrazine Catalytic Decomposition Gas Generators Use in Fuel Cells Corrosion Protection Drawbacks of Hydrazine “Green” Propellants as Hydrazine Replacements Introduction Energetic Aqueous Ionic Liquids Thermal Decomposition Catalytic Decomposition of HAN , ADN , and HNF A Hydroxyl Ammonium Nitrate ( HAN ) B Hydrazinium NitroFormate ( HNF ) C Ammonium DiNitramide ( ADN ) Development of Tools for Catalyst Evaluation The Comeback of Hydrogen Peroxide Introduction Thermal and Catalytic Decomposition Catalysts for Monopropellant Engines Kinetic Rate of Decomposition Hybrid Engine Hypergolic Bipropellant Engine Effect of Stabilizers on Catalytic Decomposition Nitrous Oxide (N 2 O) for Monopropellant Engines or Hybrid Engines Introduction Catalysts Use of N 2 O as a Monopropellant Use of N 2 O for Hybrid Engine Future Prospective Applications of Catalytic Propulsion New Energetic Liquids Catalysts for Air‐Breathing Supersonic or Hypersonic Jets Catalysts for Pulse Detonating Engine Ignition of Gaseous Hydrogen–Oxygen Mixtures Gas Generator to Power Micropumps through Small Turbines Conclusion: A Biological System using H 2 O 2 Decomposition for Tactical Defense Acknowledgement

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Section: A Shell 405 Catalyst (Usa)mentioning

confidence: 99%

Section: Homogeneous Catalysis and Coordination Chemistry Of Hydrazinementioning

confidence: 99%

Catalytic Decomposition of Energetic Compounds: Gas Generators and Propulsion1A list of abbreviations/acronyms used in the text is provided at the end of the chpater

Batonneau

Kappenstein

Keim

2008

Handbook of Heterogeneous Catalysis

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“…Reaction (1) is a highly exothermic reaction which could cause a temperature increase of up to 1273 K . The resulting high temperatures could have a significant effect on the structural properties of the catalyst and lead to a decrease in its activity .…”

Section: Introductionmentioning

confidence: 99%

Ir Impregnation on Alumina Pores: Catalyst Activity and Loss During Hydrazine Decomposition

Salimi

Pakdehi

Shekarian

2020

Propellants Explo Pyrotec

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Catalytic decomposition of hydrazine over Ir/γ‐Al2O3 was investigated using catalysts with different Ir content. The catalysts were characterized by XRD, XRF, BET, and TEM. Results indicated that with increasing Ir content from 5.6 to 40.8 wt%, the BET surface area and pore volume decreased. This decrease was more significant when Ir content increased from 34.3 to 40.8 wt%. Reactor tests also indicated that the maximum stable reactor pressure of 2180 kPa with the time of about 400 milliseconds to obtain this pressure, and the lowest catalyst loss of 11.3 wt% were obtained with 34.4 wt% Ir as optimum Ir loading.

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Inorganic Reactions

Schlögl¹,

Wagner²,

Fetzer³

et al. 1997

Handbook of Heterogeneous Catalysis

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Modelling and simulation of monopropellant hydrazine thrusters for spacecraft position control

Cited by 8 publications

References 7 publications

Catalytic Decomposition of Energetic Compounds: Gas Generators and Propulsion1A list of abbreviations/acronyms used in the text is provided at the end of the chpater

Catalytic Decomposition of Energetic Compounds: Gas Generators and Propulsion1A list of abbreviations/acronyms used in the text is provided at the end of the chpater

Ir Impregnation on Alumina Pores: Catalyst Activity and Loss During Hydrazine Decomposition

Inorganic Reactions

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