Blast
furnace sludge is a heterogeneous material generated by the
wet top gas cleaning process. It consists mainly of Fe, O, and C and
contains major amounts of Si, Al, and Mg. Besides these elements,
the sludge also contains trace metals such as Cd, Zn, and Pb. Reliable
information about the total contents and distribution of the elements
present in blast furnace sludge is of importance for hot metal production
as some of them should preferably be recycled (Fe, C) and others (Cd,
Zn, or Pb) are of environmental concern. Hence, the aim of the present
study was to investigate the composition of blast furnace sludge with
respect to the separation of desirable from undesirable elements.
For this purpose, blast furnace sludge samples have been taken and
analyzed with regard to particle size distribution (using wet sieving)
and their respective contents of Fe, Zn, Pb, Cr, Ni, Cd, and C. The
results of the analyses demonstrate that the concentration of the
elements investigated significantly depends on the particle size.
Coarser particles (>100 μm) are characterized by higher contents
of C, whereas fine grained particles (<20 μm) show an enrichment
of Fe and a significant accumulation of the heavy metals Zn, Pb, and
Cd, which is attributed to their condensation on the particles’
surfaces. The content of Cr and Ni in blast furnace sludge is largely
independent of the particle size.