“…~80% of the large cavities are filled with Se 8 while the rest ~20% with Se 12 . Despite quite long history of studies of LTA-Se fabricated by different methods (high-pressure Se melt injection [28] and vapour adsorption at different temperatures [12][13][14][15][29][30][31][32][33]), this work provides the first clear evidence for the double-Se 8 -ring-cluster formation. Slightly compressed luminescent Se 2 − anions, oriented along the LTA 4-fold axes and located in the sodalite cages, are detected via Raman polarization/orientation dependencies of LTA-Se (17), the compression being partially relaxed with a decrease in temperature producing an anomalous Se 2 − Raman downshift.…”