In the digital printing process, reliable colour reproduction is commonly achieved by printer characterisation, which defines the correspondence between the input device control values and the output colour information. The cellular Yule–Nielsen spectral Neugebauer model, together with its variants, is widely adopted in this topic because of its superb colorimetric and spectral accuracy. However, it seems that current studies have neglected an inconspicuous defect in such models when characterising printers equipped with black ink. That is, the cellular structure of these models overemphasises the sampling for dark-tone colours, and thus leads to relatively large errors in light tones. In this paper, taking a CMYK printer as an example, a simple and effective solution is proposed with no need of extra sampling. With the aid of a newly built cellular spectral Neugebauer model for the embedded CMY printer, this approach optimises the printer characterisation for light tones, slightly improves the precision for middle tones while it maintains the accuracy for dark tones. The performance of the proposed method was evaluated with regard to three different kinds of substrates and the experimental results validated its improvement in spectral printer characterisation.