Modulations in surface and aggregation properties of non-ionic surfactant Triton X-45 on addition of ionic liquids in aqueous media

Pal, Amalendu; Pillania, Ankita

doi:10.1016/j.molliq.2017.03.037

Cited by 32 publications

(15 citation statements)

References 36 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The DPH has higher CMC values than the TX–45, due to the complex structure and ionic nature of DPH. The values of CMC of pure constituents are well-matched with reported values [ 51 , 52 ]. The values of CMC of pure amphiphiles in the presence of 25 mM IL are shown in Table 1 .…”

Section: Resultssupporting

confidence: 87%

Mixed Micellization and Spectroscopic Studies of Anti-Allergic Drug and Non-Ionic Surfactant in the Presence of Ionic Liquid

2021

View full text Add to dashboard Cite

In drug delivery, surfactants are used to reduce side effects and to increase drug efficiency. The present work aimed to study the interaction of diphenhydramine hydrochloride (anti-allergic drug) with TX–45 (non-ionic surfactant) in the absence and presence of ionic liquid (1-hexyl-3-methylimidazolium chloride). The physicochemical parameters were estimated by the surface tension measurement. Various theoretical models (Clint, Rubingh, Motomura, and Maeda) were applied to determine the attractive behavior between drug and surfactant mixtures at the surface and in bulk. The drug and surfactant mixtures exhibit synergistic behavior in the absence and presence of ionic liquid. Several energetic parameters were also estimated with the assistance of regular solution approximation and pseudo phase separation model that indicate micelle formation and adsorption of surfactant at the surface is thermodynamically advantageous. The morphology of pure and mixture of amphiphiles has been estimated by the Tanford and Israelachvili theories. UV-visible spectroscopy was used to quantify the attractive behavior of the drug with surfactant with the help of a binding constant (K).

show abstract

Section: Resultssupporting

confidence: 87%

Mixed Micellization and Spectroscopic Studies of Anti-Allergic Drug and Non-Ionic Surfactant in the Presence of Ionic Liquid

2021

View full text Add to dashboard Cite

show abstract

“…The plot of ln( I 0 / I Q ) vs . [ Q ] is having a straight line, whose slope can be utilized to determine the value of N agg of surface-active molecules (Wang et al, 2007 ; Pal and Pillania, 2015b , 2017 ; Piñeiro et al, 2015 ; Singh and Kang, 2015 ; Chadha et al, 2016 ; Banjare et al, 2017 ; Pal and Punia, 2019b ).…”

Section: Methodsmentioning

confidence: 99%

“…Sun et al ( 2014 ) studied the influence of methylimidazolium based ILs having hydrophobic anions on the aggregation of Triton X-114 and concluded that both the hydrophilic and hydrophobic ILs influence the micellization behavior of Triton X-114 evident from the change in the size of micellar aggregate, change in zeta potential, cloud point as well as CMC. Pal and Pillania ( 2016a , 2017 ) utilize 1-butyl-2,3-dimethylimidazolium bromide [bdmim][Br] and 1-hexyl-2,3-dimethylimidazolium bromide [hdmim][Br] to investigate alterations in micellization behavior of Triton X-100. They also utilize 1-butyl-2,3-dimethylimidazoliumbromide [bdmim][Br] and 1-butyl- 3-methylimidazolium bromide [bmim][Br] to investigate alterations micellization behavior of Triton X-45.…”

Section: Mixed Micellization Behaviormentioning

confidence: 99%

Scrutinizing Self-Assembly, Surface Activity and Aggregation Behavior of Mixtures of Imidazolium Based Ionic Liquids and Surfactants: A Comprehensive Review

Kumar

Kaur

2021

Front. Chem.

View full text Add to dashboard Cite

The desire of improving various processes like enhanced oil recovery (EOR), water treatment technologies, biomass extraction, organic synthesis, carbon capture etc. in which conventional surfactants have been traditionally utilized; prompted various researchers to explore the self-assembly and aggregation behavior of different kinds of surface-active molecules. Ionic liquids (ILs) with long alkyl chain present in their structure constitute the advantageous properties of surfactant and ILs, hence termed as surface-active ionic liquids (SAILs). The addition of ILs and SAILs significantly influence the surface-activity and aggregation behavior of industrially useful conventional surfactants. After a brief review of ILs, SAILs and surfactants, the prime focus is made on analyzing the self-assembly of SAILs and the mixed micellization behavior of conventional surfactants with different ILs.

show abstract

“…The proclivity of amphiphilic molecules to self-aggregates can also be used to evaluate the different thermodynamic parameters. One of the thermodynamic parameters, known as Gibbs free energy (∆G o m ), was assessed for the association of singular components (IMP and TX-100) along with their blended system in different ratios using Equation ( 7) [51][52][53].…”

Section: Thermodynamic Parametermentioning

confidence: 99%

Investigation of Solution Behavior of Antidepressant Imipramine Hydrochloride Drug and Non-Ionic Surfactant Mixture: Experimental and Theoretical Study

et al. 2021

View full text Add to dashboard Cite

In this paper, the interaction of imipramine hydrochloride (IMP, antidepressant drug) and a non-ionic surfactant Triton X-100 (TX-100) mixture in five different ratios through the tensiometric method in different solvents (aqueous/0.050 mol·kg−1 aqueous NaCl/0.250 mol·kg−1 aqueous urea (U)) were examined thoroughly at a temperature of 298 K. UV–Visible studies in an aqueous system of IMP + TX-100 mixtures were also investigated and discussed in detail. The pure (IMP and TX-100) along with the mixtures’ critical micelle concentration (cmc) were assessed by a tensiometric technique. The obtained deviation of the mixtures’ cmc values from their ideal values revealed the nonideal behavior of IMP + TX-100 mixtures amongst IMP and TX-100. Compared to aqueous systems, in the presence of aqueous NaCl, several changes in micelles/mixed micelles occurred, and hence a synergism/attractive interaction amongst components was found increased while in the existence of U, the synergism/attractive interaction between them decreased. The evaluated interaction parameter (βRb) value of mixed micelles showed the attractive or synergism between the IMP and TX-100. Various evaluated thermodynamic parameters in an aqueous system showed that the mixed micellization of the IMP + TX-100 mixture was an entropically spontaneous phenomenon, although the existence of salt in all studied systems can somewhat increase the spontaneity of the micellization process and in the aqueous U system, the spontaneity of the micellization process decreased. In an aqueous system, the interaction between IMP and TX-100 was also confirmed by UV–Visible study.

show abstract

Modulations in surface and aggregation properties of non-ionic surfactant Triton X-45 on addition of ionic liquids in aqueous media

Cited by 32 publications

References 36 publications

Mixed Micellization and Spectroscopic Studies of Anti-Allergic Drug and Non-Ionic Surfactant in the Presence of Ionic Liquid

Mixed Micellization and Spectroscopic Studies of Anti-Allergic Drug and Non-Ionic Surfactant in the Presence of Ionic Liquid

Scrutinizing Self-Assembly, Surface Activity and Aggregation Behavior of Mixtures of Imidazolium Based Ionic Liquids and Surfactants: A Comprehensive Review

Investigation of Solution Behavior of Antidepressant Imipramine Hydrochloride Drug and Non-Ionic Surfactant Mixture: Experimental and Theoretical Study

Contact Info

Product

Resources

About