Molecular complexes of octafluoronaphthalene with catenated chalcogen–nitrogen compounds C6H5–X–NSN–SiMe3 (X=S, Se)

Makarov, Alexander Yu.; Lork, Enno; Mews, Rüdiger; Zibarev, Andrey V.

doi:10.1016/j.jfluchem.2005.11.021

Cited by 8 publications

(1 citation statement)

References 14 publications

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“…The molecular structures and packing of materials with alternating double-bonded N and chalcogen atoms (including S) have been the subject of a number of papers [for examples, see Bagryanskaya et al (1997), Bagryanskaya (2009), Makarov et al (2006) and Melen et al (2012Melen et al ( , 2013]. These included the molecular structures and packing of a number of related 1,3diaza-2,4-dithiabuta-1,2-dienes.…”

Section: Introductionmentioning

confidence: 99%

The structure of the first stable monosubstituted sulfur diimide

Jones¹

2015

Acta Crystallogr C

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The title compound, 4-(4-methylphenyl)-1,3-diaza-2,4-dithiabuta-1,2-diene, C7H8N2S2, was the first example of a stable monosubstituted sulfur diimide to be documented [Jones (1988). PhD thesis, Imperial College, University of London, England]. Although a partial description of this structure was published previously, the full details are presented here. This allows a detailed comparison against the only other example of this system published to date, highlighting differences in bonding, conformation and packing.

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Section: Introductionmentioning

confidence: 99%

The structure of the first stable monosubstituted sulfur diimide

Jones¹

2015

Acta Crystallogr C

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Recent Advances of Structural Chemistry of Organoselenium and Organotellurium Compounds

Nakanishi

Hayashi

Hashimoto

et al. 2014

Patai's Chemistry of Functional Groups

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The recent advances of structural chemistry of organoselenium and organotellurium compounds are reviewed. The basic concepts of structural chemistry of the compounds are well summarized in Chapter 3 of Volume 1 in this series. About 9,000 structures for the compounds have been reported since then, therefore only selected results can be discussed here. Such compounds are expected to contain at least one CE (E = Se or Te) bond, although those with no CE bonds are also discussed, as necessary. Compounds containing CE (E = Se and Te) are discussed in some detail. Structures of unstable and/or reactive species are explained in detail, which are stabilized by the formation of dimers or higher oligomers or using large protecting groups. Bis‐selenides and bis‐tellurides and the derivatives at the naphthalene 1,8‐positions and the related systems are discussed in detail. The compounds containing hypervalent interactions are also discussed in detail. The idea is applied to the intramolecular and intermolecular linear interactions in crystals. In this connection, the extended hypervalent interactions are also explained in detail for the linear interactions longer than three, exemplified by typical cases and unique cases in crystals.

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