The present study evaluated the concentrations, spatial distribution, seasonal variations, potential sources, and risk assessment of organic/ inorganic pollutants in ambient air of Tehran city. Totally, 180 air samples were taken from 9 sampling stations from March 2018 to March 2019 and were analyzed to determine the concentrations of organic pollutants (BTEX compounds and PM 2.5 -bound PAHs) plus inorganic pollutants (PM 2.5 -bound metals and asbestos fibers). The results revealed that the mean concentrations of P PAHs, BTEX, P heavy metals, and asbestos fibers were 5.34 ng/m 3 , 60.55 lg/m 3 , 8585.12 ng/m 3 , and 4.13 fiber/ml in the cold season, respectively, and 3.88 ng/m 3 , 33.86 lg/m 3 , 5682.61 ng/m 3 , and 3.21 fiber/ml in the warm season, respectively. Source apportionment of emission of the air pollutants showed that PAHs are emitted from diesel vehicles and industrial activities. BTEX and asbestos are also released mainly by vehicles. The results of the inhalation-based risk assessment indicated that the carcinogenic risk of PAHs, BTEX, and asbestos exceeded the recommended limit by The US environmental protection agency (US EPA) and WHO Majid Kermani and Zahra Asadgol are considered as joint first authors.