The Korea Atomic Energy Research Institute (KAERI) has developed the DeCART2D 2-dimensional (2D) method of characteristics (MOC) transport code and the MASTER nodal diffusion code and has established its own two-step procedure. For design code licensing, KAERI prepared a critical experiment on the verification and validation (V&V) of the DeCART2D code. DeCART2D is able to perform the MOC calculation only for 2D nuclear fuel systems, such as the fuel assembly. Therefore, critical buckling in the vertical direction is essential for comparison between the results of experiments and DeCART2D. In this study, the B1 theory-augmented Monte Carlo (MC) method was adopted for the generation of critical buckling. To examine critical buckling using the B1 theory-augmented MC method, TCA critical experiment benchmark problems were considered. Based on the TCA benchmark results, it was confirmed that the DeCART2D code with the newly-generated critical buckling predicts the criticality very well. In addition, the critical buckling generated by the B1 theory-augmented MC method was bound to uncertainties. Therefore, utilizing basic equations (e.g., SNU S/U formulation) linking input uncertainties to output uncertainties, a new formulation to estimate the uncertainties of the newly generated critical buckling was derived. This was then used to compute the uncertainties of the critical buckling for a TCA critical experiment, under the assumption that nuclear cross-section data have uncertainties.