Aircraft soot has
a significant effect on the air quality and human
health. The aim of this study is to investigate the evolution of soot
morphology in free jet laminar diffusion flames between Chinese traditional
aviation kerosene RP-3 and algae-based aviation biofuels. The differences
in height, profile, and structural properties of soot between the
RP-3 flame and biofuel flame are determined. A laboratory-made probe
sampling method was applied for soot sample collection. Transmission
electron microscopy (TEM), high-resolution transmission electron microscopy
(HRTEM), X-ray diffraction (XRD), and elemental analyzers were used
to analyze the collected soot particles. The average particle size
of soot increases first and then decreases in both flames, and the
size of biofuel primary particles is smaller than that of jet fuel
RP-3 particles along the same flame height. At the flame tip, the
primary particle sizes of RP-3 soot and biofuel soot are 22.7 and
15.6 mm, respectively. In comparison with the RP-3 soot, the nanostructure
of biofuel soot particles along the same flame height exhibits a shorter
fringe lattice, a larger fringe tortuosity, and a larger interlayer
spacing, which indicate a higher degree of oxidation reactivity. Meanwhile,
RP-3 soot particles have a lower H/C atom ratio and have greater intensity
in X-ray diffraction, which indicates a more orderly and compact lattice
structure. This study provides some references in studying the algae-based
biofuel with regard to soot formation.