2004
DOI: 10.1016/j.jnucmat.2003.10.015
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Morphological evolution of alteration layers formed during nuclear glass alteration: new evidence of a gel as a diffusive barrier

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Cited by 88 publications
(87 citation statements)
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“…If silicon dissolved from the outer surface of the gel, Si should not diffuse but be directly released into solution. So, Si should prefer to dissolve from the outer surface of the gel, and experiments validate this [52]. Secondly, GM models consider the gel as a constant composition boundary, but more resent research found that the gel morphology is changing constantly during glass alteration, and even can close the "kinetic reaction path" [53,54,61,62].…”
Section: A C C E P T E D Accepted Manuscriptmentioning
confidence: 95%
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“…If silicon dissolved from the outer surface of the gel, Si should not diffuse but be directly released into solution. So, Si should prefer to dissolve from the outer surface of the gel, and experiments validate this [52]. Secondly, GM models consider the gel as a constant composition boundary, but more resent research found that the gel morphology is changing constantly during glass alteration, and even can close the "kinetic reaction path" [53,54,61,62].…”
Section: A C C E P T E D Accepted Manuscriptmentioning
confidence: 95%
“…There is no general agreement on the cause of this rate reduction. Two theories suggest that it is due to:(a) chemical affinity change [13,[42][43][44][45][46][47]; and(b) diffusion barrier effect [14,15,48,[51][52][53][54], or the combination of both [17,49,50].…”
Section: Rate Drop and Residual Ratementioning
confidence: 99%
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