Morphology in Multilayer Blown Films of Polypropylene and Ethylene-Octene Copolymer Blends

Abstract

In this work the microstructure of multilayer blown films consisting of a core layer placed between two external ones is studied. The core layer is a blend with 70 % (w/w) of a homopolypropylene PP and 30 % of a metallocene-catalyzed ethylene-octene copolymer mEOC (LLDPE or VLDPE), whereas the external symmetrical layers are composed of LLDPE or they have the same composition as the core layer. The PP and PE crystalline phases formed during the film blowing were investigated by thermal analysis, mechanical properties, TEM morphology and X-ray diffraction pole figures. These films successfully combine the high mechanical strength of PP with the quasi-isotropic behavior of blown PE. Multilayer film containing PP/mEOC blends, particularly blends of PP70/LLDPE30, show better balanced tensile properties when compared at crossed directions. The presence of VLDPE in the blends shifts downwards the melting and crystallization temperatures and crystallinity of PP. X-Ray pole figures suggest the occurrence of epitaxial crystallization of the PE phase upon the PP crystals in these PP/mEOC blend films.

Direct relationship between crystalline structure and part deformation of polypropylene copolymer parts fabricated by material extrusion additive manufacturing

“… is the weight fraction of PP or PE block in copolymer. for PE and PP are 293 44 and 165 J/g, 45 respectively.…”

Effects of different polyolefin copolymers on properties of melt mixed polypropylene blends

“…Moreover, the impact PP copolymers can be produced in a two‐reactor system to yield a homopolymer with an ethylene‐propylene rubber 19,20 . Among these copolymers, octene‐based ethylene copolymers have received huge attention owing to their unique molecular characteristics and their physical properties lie between plastic and elastomer 21,22 . Octene‐based ethylene copolymers also provide better impact improvement, lower cost, and mild processing with twin‐screw extruder than other rubber copolymers 19 .…”

“…19,20 Among these copolymers, octene-based ethylene copolymers have received huge attention owing to their unique molecular characteristics and their physical properties lie between plastic and elastomer. 21,22 Octene-based ethylene copolymers also provide better impact improvement, lower cost, and mild processing with twin-screw extruder than other rubber copolymers. 19 Moreover, these copolymers possess narrow molecular weight distribution and controlled comonomer distributions; thereby, they promote tensile strength for PP homopolymer considerably.…”