Developing
high-performance filtration materials is crucial for
the effective removal of airborne particulate matter. However, balancing
the filtration efficiency and pressure drop in these filtration materials
and simultaneously achieving high efficiency and low resistance remain
challenging. In this study, we observed that the addition of poly(methylhydrosiloxane)
(PHMS) contributes to the refinement of PS fibers and can improve
the hydrophobicity of the membrane. Therefore, PHMS-doped polystyrene
(PS) multiscale nanofiber composite membranes were prepared by electrospinning,
and their filtration performance was systematically investigated.
By integrating fibers with diameters 62 and 430 nm, doped with 5 and
20% PHMS, respectively, a multiscale nanofibre membrane was constructed,
which achieved high filtration efficiency (99.90% for PM0.3), low resistance (pressure drop 63 Pa), and a quality factor of
0.0893 Pa–1. After 10 filtration cycles, the membrane
sustained 99% efficiency, surpassing that of commercial filters in
terms of long-term filtration performance. The filtration efficiency
and pressure drop of the multiscale nanofiber membrane were simulated
by establishing an airflow field, and the simulation results confirmed
the excellent filtration performance. The present study introduces
an innovative methodology for fabricating high-efficiency and low-resistance
nanofibers as air filtration materials.