Multifunctional SnO2/3D graphene hybrid materials for sodium-ion and lithium-ion batteries with excellent rate capability and long cycle life

Lee, Jung-In; Song, Junhua; Cha, Younghwan; Fu, Shaofang; Zhu, Chengzhou; Li, Xin; Lin, Yuehe; Song, Min‐Kyu

doi:10.1007/s12274-017-1756-3

Cited by 68 publications

(41 citation statements)

References 79 publications

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“…The comparison of electrochemical performance on tin oxide/graphene or reduced graphene oxide composite electrode is given in Table S1. From Table S1, we can see that the rate performance of the SnO 2 @Glu/G composite electrode is better than that of SnO 2 electrode just modified by graphene or reduced graphene oxide ,…”

Section: Resultsmentioning

confidence: 99%

Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

et al. 2018

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SnO 2 /carbon composites including amorphous carbon and graphene or carbon nanotubes are synthesized by a gas-liquid interfacial approach and subsequent annealing process. The effect of the carbon source and the conductive additive on the electrochemical performance is investigated by galvanostatic charge-discharge tests. SnO 2 @Glucose/Graphene (SnO 2 @Glu/G) composites as anodes of sodium-ion batteries show the best electrochemical performance, delivering 306 mA h g À1 after 100 cycles at 0.1 A g À1 between 0.01-3 V, while exhibiting 278 and 226 mA h g À1 at 1 and 2 A g À1 , respectively. The mechanism of improved electrochemical performance for graphene is researched in detail. The results reveal a porous structure with fine SnO 2 particles due to the introduction of graphene oxide, and an effective electron charge transfer network from the graphene increases its reversible capacity, rate performance and cycling performance.[a] S.

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Section: Resultsmentioning

confidence: 99%

Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

et al. 2018

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“…As shown in Figure 3d, the C 1s peak of SnO 2 /NGA comprises the four binding states, namely CÀ C (284.6 eV), CÀ N (285.2 eV), CÀ OÀ C (epoxy groups, 286.2 eV), and OÀ C=O (carboxyl, 288.7 eV) can be discerned. [27,37,38] In the case of SnO 2 @Sn/NGA, (Figure 3e) only CÀ C (284.6 eV), CÀ N (285.2 eV), and CÀ OÀ C (epoxy groups, 286.2 eV) can be discerned. The areal percentage of the O 1s peak is reduced from 36.2 % for the SnO 2 /NGA to 21.3 % for the SnO 2 @Sn/NGA.…”

Section: Resultsmentioning

confidence: 99%

Plasma‐Enabled Ternary SnO₂@Sn/Nitrogen‐Doped Graphene Aerogel Anode for Sodium‐Ion Batteries

Wang

Liu

et al. 2020

ChemElectroChem

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SnO2‐based sodium‐ion batteries usually suffer from rapid capacity fading during the sodiation/desodiation caused by aggregation and cracking of Sn and irreversible formation of Na2O. In this respect, we design a ternary SnO2@Sn core‐shell structure decorated on a nitrogen‐doped graphene aerogel (SnO2@Sn/NGA), which is fabricated by using a microwave plasma‐based process. The converted Na2O can prevent agglomeration of Sn, thus stabilizing the structure during the cycles. Close contact between Na2O and Sn ensures Na+ ion diffusion to the Sn core and reversible conversion of Sn↔ SnO2. Moreover, the deoxygenation effect of the plasma on NGA improves its degree of graphitization and electrical conductivity, which substantially improves the electrode rate performance. As a result, the SnO2@Sn/NGA anode delivers a high initial discharge capacity of 448.5 mAh g−1 at 100 mA g−1. Importantly, this unique nanohybrid electrode design can be extended to advanced anode materials for both lithium‐ and sodium‐ion batteries.

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“…It demonstrates two cathodic plateaus close to 1.25 and 0.5 V in the initial discharge process, but only a cathodic plateau close to 0.5 V in the 5 th and 10 th discharge curves. It can be concluded that the plateau near 1.25 V corresponds to the irreversible sodiation process (SnO 2 +4Na + +4e − →Sn+2Na 2 O), and the plateau near 0.5 V corresponds to the formation of SEI and reversible Na‐alloying process (Sn+ x Na + + x e − ⇆Na x Sn) ,,. After the initial 10 cycles at current density of 0.05 A g −1 , SnO 2 /rGO xerogel presents excellent rate cyclic performance at the increased current density of 0.5 A g −1 , without capacity loss for 260 cycles (Figure b).…”

Section: Resultsmentioning

confidence: 99%

“…To resolve the above‐mentioned problems, extensive works have been reported to enhance the cycling stability and rate capability of tin‐based anode materials in the recent years . including nanoparticles, nanotubes, nanosheets, nanowires, and hollow nanospheres to buffer the volumetric expansion and shorten the lithium diffusion pathway.…”

Section: Introductionmentioning

confidence: 99%

Freeze‐Drying‐Assisted Synthesis of Porous SnO₂/rGO Xerogels as Anode Materials for Highly Reversible Lithium/Sodium Storage

Jiang

et al. 2018

ChemElectroChem

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Three‐dimensional porous SnO2/rGO xerogels with superior cycling performance in lithium‐ion batteries (LIBs) and sodium‐ion batteries (SIBs) are fabricated through a freeze‐drying‐assisted method. SnO2 nanoparticles (5 nm in diameter) are homogeneously attached to the surface of graphene sheets without self‐aggregation. The heterostructured SnO2/rGO xerogel possesses numerous micron‐sized pores that can efficiently buffer the volumetric change of SnO2 during the charge/discharge process and provide multidimensional channels, improving the conductivity between active materials and electrolyte. The SnO2/rGO xerogel exhibits excellent electrochemical performance, both in LIBs and SIBs, owing to its particular porous structure. For LIBs, it delivers a high initial discharge capacity of 1670.5 mAh g−1 in the first cycle and remains at 1139.4 mAh g−1 after 166 cycles at a current density of 0.1 A g−1. The SnO2/rGO xerogel also delivers a high discharge capacity of 189.4 mAh g−1 without capacity loss over 266 cycles at a current density of 0.5 A g−1 for SIBs. The SnO2/rGO xerogel can be used as an electrode material in both LIBs and SIBs, and can maintain an excellent rate performance and cyclic performance, owing to the abundant porosity and high conductivity.

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Multifunctional SnO2/3D graphene hybrid materials for sodium-ion and lithium-ion batteries with excellent rate capability and long cycle life

Cited by 68 publications

References 79 publications

Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Plasma‐Enabled Ternary SnO₂@Sn/Nitrogen‐Doped Graphene Aerogel Anode for Sodium‐Ion Batteries

Freeze‐Drying‐Assisted Synthesis of Porous SnO₂/rGO Xerogels as Anode Materials for Highly Reversible Lithium/Sodium Storage

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Multifunctional SnO2/3D graphene hybrid materials for sodium-ion and lithium-ion batteries with excellent rate capability and long cycle life

Cited by 68 publications

References 79 publications

Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Plasma‐Enabled Ternary SnO2@Sn/Nitrogen‐Doped Graphene Aerogel Anode for Sodium‐Ion Batteries

Freeze‐Drying‐Assisted Synthesis of Porous SnO2/rGO Xerogels as Anode Materials for Highly Reversible Lithium/Sodium Storage

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Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Optimization of SnO₂ Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

Plasma‐Enabled Ternary SnO₂@Sn/Nitrogen‐Doped Graphene Aerogel Anode for Sodium‐Ion Batteries

Freeze‐Drying‐Assisted Synthesis of Porous SnO₂/rGO Xerogels as Anode Materials for Highly Reversible Lithium/Sodium Storage